Home
Class 12
CHEMISTRY
A thermodynamic cycle in the pressure (P...

A thermodynamic cycle in the pressure (P) - volume (V) plane is given below :

AB and CD are isothermal processes while BC and DA are adiabatic processes. The same cycle in the temperature (T) - entropy (S) plane is :

A

B

C

D

Text Solution

Verified by Experts

The correct Answer is:
A

AB is isothermal reversible expansion process i.e. `Delta`T = 0 and S increases as there is increase in volume.
BC is adiabatic reversible expansion process
`(q_("rev")=0)` i.e., temperature decreases and `DeltaS=0`.
CD is isothermal reversible compression process i.e. `DeltaT = 0` and S decreases as there is decrease in volume.
DA is adiabatic reversible compression process `(q_("rev") = 0)` i.e. temperature decreases and `DeltaS = 0. `
Promotional Banner

Topper's Solved these Questions

  • QUESTION PAPER 2020

    KVPY PREVIOUS YEAR|Exercise PART-II : CHEMISTRY |5 Videos
  • QUESTION PAPER 2020

    KVPY PREVIOUS YEAR|Exercise PART-I (CHEMISTRY )|20 Videos
  • QUESTION PAPER 2013

    KVPY PREVIOUS YEAR|Exercise PART-II ( CHEMISTRY)|10 Videos
  • SOLVED PAPER 2018

    KVPY PREVIOUS YEAR|Exercise EXAMPLE|30 Videos

Similar Questions

Explore conceptually related problems

Find work in the given cycle, If AB is isothermal process and CA is adiabatic.

A monoatomic ideal is used as the working substance for the carnot cycle shown in the figure. Processes AB and CD are isothermal, while processes BC and DA are adiabatic. During process AB, 400 J of work is done by the gasd on the surroundings. How much heat is expelled by the gas during process CD?

Two moles of an ideal gas goes under the process shown in figure. AB and CD are reversible adiabatic process. The efficiency of the cycle is

p-T diagram of one mole of an ideal monatomic gas is shown. Processes AB and CD are adiabatic. Work done in the complete cycle is

Two samples 1 and 2 are initially kept in the same state. The sample 1 is expanded through an isothermal process where as sample 2 through an adiabatic process upto the same final volume. The final temperature in process 1 and 2 are T_(1) and T_(2) respectively, then

The P - V graph of an ideal gas cycle is shown here as below. The adiabatic process is described by

An ideal gas is taken through a thermodynamic cycle ABCDA. In state A pressure and volume are P_(0) and V_(0) respectively. During the process A rarr B , work done by the gas is zero and its temperature increases two fold. During the process B rarr C , internal energy of the gas remains constant but work done by it is W_(BC) = – P_(0)V_(0) ln2 . In the process C rarr D , the temperature decreases by 50% while the volume does not change. In the process D rarr A the temperature of the gas does not change. (a) Draw pressure – volume (P–V) and pressure – density (P – rho) graph for the cyclic process. (b) Calculate work done on the gas during the cycle.

Entropy ( S ) is a thermodynamic variable like pressure P , volume V and temperature T . Entropy of a thermodynamic system is a measure of disorder of molecular motion. Greater is disorder , greater is entropy. Change in entropy of a thermodynamic system is the ratio of heat supplied to absolute temperature.In an adiabatic reversible process, entropy remains constant while in any irreversible process entropy increases. In nature the processes are irreversible , therefore entropy of universe is continuoulsy increasing. The unit of entropy in S-I system is -