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The reaction of toluene with chlorine in...

The reaction of toluene with chlorine in the presence of ferric chloride gives mainly

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Methylamine dissolves in water to give methylammonium hydroxide, which ionises to give methylammonium and hydroxide ions.
`underset("Methylamine")(CH_(3)overset(..)NH_(2))+H_(2)Oiffunderset("Methylammonium hydroxide")([CH_(3)NH_(3)]^(+)OH)iff[CH_(3)NH_(3)]^(+)+OH^(-)`
Due to the formation of `OH^(-)`, ions they can precipitate out iron aluminium, chromium etc., from their salts.
`[CH_(3)NH_(3)]^(+)OH^(-)+FeCl_(3)rarrFe(OH)_(3)darr+CH_(3)NH_(3)Cl`
Ferric hydroxide being unstable can be considered as hydrated ferric oxide.
`2Fe(OH)_(3)rarrFe_(2)O_(3)+3H_(2)O`
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BETTER CHOICE PUBLICATION-AMINES -QUESTION BANK (13.3 CHEMICAL REACTIONS)
  1. Why 2^@ amine is more basic than 1^@ and 3^@ amine ?

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  2. Why benzylamine more basic than aniline?

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  3. The reaction of toluene with chlorine in the presence of ferric chlori...

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  4. Amino group in aniline is o, p-directing and activating in electroph...

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  5. Aniline does not undergo Friedel-Crafts reaction. Explain.

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  6. Acylation of —NH2 group in aniline reduces its reactivity in electroph...

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  7. What is Carbylamine reaction ? How is it used to distinguish primary a...

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  8. How will you convert ethylamine to ethyl alcohol?

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  9. How will you convert : Aniline into benzonitrile

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  10. How will you convert : Aniline into benzonitrile

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  11. How will you convert : Aniline into a acetanilide

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  12. Write short note on acetylation of amines.

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  13. How 1^@ amine reacts with nitrous acid ?

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  14. How 2^@ amine reacts with nitrous acid ?

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  15. How 3^(@) amine reacts with nitrous acid ?

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  16. Give one chemical test to distinguish between the following pairs of c...

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  17. Give one chemical test to distinguish between the following pairs of c...

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  18. Give one chemical test to distinguish between the following pairs of c...

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  19. Give one chemical test to distinguish between the following pairs of c...

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  20. Give one chemical test to distinguish between the following pairs of c...

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