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How 3^(@) amine reacts with nitrous acid...

How `3^(@)` amine reacts with nitrous acid ?

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`3^(@)` aliphatic amines react with nitrous in cold to form salts which decompose on warming to give nitrosoamine and alcohol.
`R_(3)N+HNO_(2)rarrR_(3)NHNO_(2)overset("Warm")rarrunderset("Nitrosoamine")(R_(2)N-N=O)+underset("Alcohol")(ROH)`
`3^(@)` aromatic amines react with nitrous acid to give coloured substituted nitroso compounds.
These undergo electrophilic substitution of nitrosoanium ion at the p-position of the benzene ring.
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Knowledge Check

  • Ethylamine reacts with nitrous acid to form

    A
    `C_2H_5OH`
    B
    `C_2H_5OH, N_2, H_2O`
    C
    `C_2H_5N_2Cl`
    D
    `C_2H_5NHO, NH_3`
  • Benzylamine react with nitrous acid to form.

    A
    azobenzene
    B
    benzene
    C
    benzyl alcohol
    D
    phenol
  • The gas evolved when methylamine reacts with nitrous acid is

    A
    `NH_3`
    B
    `N_2 `
    C
    `H_2`
    D
    `C_2H_6`
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