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A closed vessel contains a mixture of tw...

A closed vessel contains a mixture of two diatomic gases `A` and `B`. Molar mass of `A` is 16 times that of `B` and mass of gas `A` contained in the vessel is 2 times that of `B`. Which of the following statements are correct ?

A

Average kinetic energy per molecules of `A` is equal to that of `B`

B

Root mean square value of translational velocity of `B` is four times that of `A`

C

Pressure exerted by `B` is eight times of that exerted by `A`

D

Number of molecules of `B` in the cylinder is eight times that of `A`

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To solve the problem, we need to analyze the given information about the two diatomic gases A and B, specifically their molar masses and the relationship of their masses in the closed vessel. ### Step-by-Step Solution: 1. **Identify the Molar Masses**: - Let the molar mass of gas B be \( M_B \). - According to the problem, the molar mass of gas A is \( M_A = 16 \times M_B \). 2. **Identify the Masses of the Gases**: - Let the mass of gas B be \( m_B \). - The problem states that the mass of gas A is \( m_A = 2 \times m_B \). 3. **Calculate the Number of Moles**: - The number of moles of gas A (\( n_A \)) can be calculated using the formula: \[ n_A = \frac{m_A}{M_A} = \frac{2 \times m_B}{16 \times M_B} = \frac{2}{16} \cdot \frac{m_B}{M_B} = \frac{1}{8} \cdot n_B \] - Where \( n_B \) is the number of moles of gas B: \[ n_B = \frac{m_B}{M_B} \] 4. **Find the Ratio of Moles**: - From the above calculation, we find: \[ n_B = 8 \times n_A \] - This means the number of moles of gas B is 8 times that of gas A. 5. **Calculate the Root Mean Square Speed**: - The formula for root mean square speed (\( v_{rms} \)) is given by: \[ v_{rms} = \sqrt{\frac{3RT}{M}} \] - For gas A: \[ v_{rms, A} = \sqrt{\frac{3RT}{M_A}} = \sqrt{\frac{3RT}{16M_B}} \] - For gas B: \[ v_{rms, B} = \sqrt{\frac{3RT}{M_B}} \] 6. **Find the Ratio of \( v_{rms} \)**: - The ratio of \( v_{rms} \) of gas B to gas A is: \[ \frac{v_{rms, B}}{v_{rms, A}} = \frac{\sqrt{\frac{3RT}{M_B}}}{\sqrt{\frac{3RT}{16M_B}}} = \sqrt{16} = 4 \] - This means the root mean square speed of gas B is 4 times that of gas A. 7. **Conclusion**: - Based on the calculations, we can conclude: - The number of moles of gas B is 8 times that of gas A. - The root mean square speed of gas B is 4 times that of gas A. - Therefore, the correct statement is that the number of moles of gas B is 8 times that of gas A. ### Summary of Correct Statements: - The first, second, and third statements are incorrect. - The fourth statement is correct.

To solve the problem, we need to analyze the given information about the two diatomic gases A and B, specifically their molar masses and the relationship of their masses in the closed vessel. ### Step-by-Step Solution: 1. **Identify the Molar Masses**: - Let the molar mass of gas B be \( M_B \). - According to the problem, the molar mass of gas A is \( M_A = 16 \times M_B \). ...
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ALLEN-GEOMETRICAL OPTICS-EXERCISE -02
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  10. The indicator diagram for two processes 1 and 2 carrying on an ideal g...

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  11. An ideal monoatomic gas undergoes a cyclic process ABCA as shown in th...

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  12. Logarithms of readings of pressure and volume for an ideal gas were pl...

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