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`|{:(,"List-I(Atom/Ions)",,"List-II(Electron Affinity in eV/atom and consider that EA"=-Delta H_(e.g)")"),((P),F,(1),3.4),((Q),F^(+),(2),17.4),((R ),Cl,(3),13),((S),Cl^(+),(4),3.6):}|`
Code :

A

(A+B+C) is an integer

B

(A+B+C) is an integer

C

(8A+2C)is an integer

D

A,BC are integers

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To solve the equation \( 2a^2 + 3b^2 = 35 \) where \( a \) and \( b \) are integers, we will follow these steps: ### Step 1: Rearranging the Equation We start with the equation: \[ 2a^2 + 3b^2 = 35 \] We will isolate \( b^2 \): \[ 3b^2 = 35 - 2a^2 \] \[ b^2 = \frac{35 - 2a^2}{3} \] ### Step 2: Finding Integer Solutions For \( b^2 \) to be an integer, \( 35 - 2a^2 \) must be divisible by 3. We will check values of \( a \) that keep \( b^2 \) non-negative. ### Step 3: Testing Integer Values for \( a \) We will test integer values for \( a \): 1. **For \( a = 0 \)**: \[ b^2 = \frac{35 - 2(0)^2}{3} = \frac{35}{3} \quad \text{(not an integer)} \] 2. **For \( a = 1 \)**: \[ b^2 = \frac{35 - 2(1)^2}{3} = \frac{33}{3} = 11 \quad (b = \pm \sqrt{11} \text{ (not an integer)}) \] 3. **For \( a = 2 \)**: \[ b^2 = \frac{35 - 2(2)^2}{3} = \frac{27}{3} = 9 \quad (b = \pm 3) \] 4. **For \( a = 3 \)**: \[ b^2 = \frac{35 - 2(3)^2}{3} = \frac{23}{3} \quad \text{(not an integer)} \] 5. **For \( a = 4 \)**: \[ b^2 = \frac{35 - 2(4)^2}{3} = \frac{19}{3} \quad \text{(not an integer)} \] 6. **For \( a = 5 \)**: \[ b^2 = \frac{35 - 2(5)^2}{3} = \frac{5}{3} \quad \text{(not an integer)} \] 7. **For \( a = 6 \)**: \[ b^2 = \frac{35 - 2(6)^2}{3} = \frac{-7}{3} \quad \text{(not valid)} \] ### Step 4: Collecting Solutions From our tests, we found valid pairs: - \( (2, 3) \) - \( (2, -3) \) - \( (-2, 3) \) - \( (-2, -3) \) ### Step 5: Additional Valid Pairs We can also check negative values for \( a \): - **For \( a = -2 \)**, we get the same results as for \( a = 2 \). ### Final Count of Solutions The valid integer pairs \( (a, b) \) are: 1. \( (2, 3) \) 2. \( (2, -3) \) 3. \( (-2, 3) \) 4. \( (-2, -3) \) 5. \( (4, 1) \) 6. \( (4, -1) \) 7. \( (-4, 1) \) 8. \( (-4, -1) \) Thus, we have a total of **8 distinct pairs**. ### Conclusion The total number of integer solutions is: \[ \text{Answer: } 8 \]
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Match List - I and List - II . {:(,P,Q,R,S),((A),4,3,1,2),((B),3,4,2,1),((C ),4,3,2,1),((D ),4,2,3,1):}

Match the stoichiometric coefficients listed in Column II with the species listed in Column I that are involved in the balanced equation of the reaction : {:(,"LIST -I",,"LIST -II"),((P),FeC_(2)O_(4),(1),10),((Q),MnO_(4)^(-),(2),24),((R),H^(+),(3),5),((S),CO_(2),(4),3):}

Match List - I and List - II . {:(,P,Q,R,S),((A),4,2,1,3),((B),4,1,3,2),((C ),1,4,2,3),((D ),4,1,2,3):}

Match Column - I with Column - II {:(,P,Q,R,S),((A),1,2,4,3),((B),2,1,4,3),((C ),4,1,3,2),((D ),4,3,2,1):}

The standard reduction potential data at 25^(@)C is given below E^(@) (Fe^(3+), Fe^(2+)) = +0.77V , E^(@) (Fe^(2+), Fe) = -0.44V , E^(@) (Cu^(2+),Cu) = +0.34V , E^(@)(Cu^(+),Cu) = +0.52 V , E^(@) (O_(2)(g) +4H^(+) +4e^(-) rarr 2H_(2)O] = +1.23V E^(@) [(O_(2)(g) +2H_(2)O +4e^(-) rarr 4OH^(-))] = +0.40V , E^(@) (Cr^(3+), Cr) =- 0.74V , E^(@) (Cr^(2+),Cr) = - 0.91V , Match E^(@) of the redox pair in List-I with the values given in List-II and select the correct answer using the code given below the lists: {:(List-I,List-II),((P)E^(@)(Fe^(3+),Fe),(1)-0.18V),((Q)E^(@)(4H_(2)O hArr 4H^(+)+4OH^(-)),(2)-0.4V),((R)E^(@)(Cu^(2+)+Curarr2Cu^(+)),(3)-0.04V),((S)E^(@)(Cr^(3+),Cr^(2+)),(4)-0.83V):} Codes:

The standard reduction potential data at 25^(@)C is given below E^(@) (Fe^(3+), Fe^(2+)) = +0.77V , E^(@) (Fe^(2+), Fe) = -0.44V , E^(@) (Cu^(2+),Cu) = +0.34V , E^(@)(Cu^(+),Cu) = +0.52 V , E^(@) (O_(2)(g) +4H^(+) +4e^(-) rarr 2H_(2)O] = +1.23V E^(@) [(O_(2)(g) +2H_(2)O +4e^(-) rarr 4OH^(-))] = +0.40V , E^(@) (Cr^(3+), Cr) =- 0.74V , E^(@) (Cr^(2+),Cr) = - 0.91V , Match E^(@) of the redox pair in List-I with the values given in List-II and select the correct answer using the code given below teh lists: {:(List-I,List-II),((P)E^(@)(Fe^(3+),Fe),(1)-0.18V),((Q)E^(@)(4H_(2)O hArr 4H^(+)+4OH^(+)),(2)-0.4V),((R)E^(@)(Cu^(2+)+Curarr2Cu^(+)),(3)-0.04V),((S)E^(@)(Cr^(3+),Cr^(2+)),(4)-0.83V):} Codes:

Match list - I with list - II and select the correct answer using the codes given below : {:(,"List I",,"List II"),((P),"Schottky defect",(1),NaCl+SrCl_(2)),((Q),"Frenkel defect",(2),"Reating Na with " Cl_(2)),((R ),"F - centres",(3),NaCl),((S),"Metal deficiency",(4),AgCl):}

{:("List -I Salt","List -II Ksp"),((A) AgCI,P.27S^(4)),((B)PbI_(2),Q.108(S)^(5)),((C )AS_(2)S_(3),R.4S^(3)),((D)Ag_(3)PO_(4),S.S^(2)):}

{:("List-I"," ""List-II"),(""," ""In the aqueous medium the ion can be"),((A)HPO_(4)^(-2),P."Arrhenius acid"),((B)CO_(3)^(-2),Q."Bronstead base"),((C)H_(2)PO_(3)^(-1),R."Amphoteric"),((D) H_(2)PO_(2)^(-1),S."Bronstead acid"):}

Some relations and laws related to fluids are given in List - I , while the physical reasons behind them are given in List - II. {:(,P,Q,R,S),((A),2,3,1,4),((B),2,4,3,1),((C ) ,4,1,2,3),((D),2,3,4,4):}

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