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Which of the following statements is COR...

Which of the following statements is CORRECT for
`F_(3)C-CF_2-CF_(3)`

A

All C-F bond lengths are identical

B

Two C-F bonds attached to middle C-atoms are longer compared to other C-F bond at the terminal C-atoms

C

Two C-F bonds attached to middle C-atom are shorter comparted to other C-F bond at ther terminal C-atoms

D

None is correct

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct statement regarding the compound \( F_3C-CF_2-CF_3 \), we will analyze the structure and bonding of the carbon-fluorine (C-F) bonds in the compound step by step. ### Step-by-Step Solution: 1. **Identify the Structure**: The compound \( F_3C-CF_2-CF_3 \) consists of three carbon atoms, with the first carbon (\( C_1 \)) bonded to three fluorine atoms (\( F_3 \)), the second carbon (\( C_2 \)) bonded to two fluorine atoms (\( CF_2 \)), and the third carbon (\( C_3 \)) bonded to three fluorine atoms (\( F_3 \)). 2. **Determine Hybridization**: Each carbon atom in the compound forms four sigma bonds. Since there are no double or triple bonds present, we can conclude that: - Each carbon is \( sp^3 \) hybridized because \( sp^3 \) hybridization occurs when a carbon atom forms four single sigma bonds. 3. **Analyze the C-F Bonds**: Since all carbon atoms are \( sp^3 \) hybridized, the C-F bonds are formed using the \( sp^3 \) hybridized orbitals of the carbon atoms. This means that: - Each C-F bond is formed by the overlap of an \( sp^3 \) hybrid orbital from carbon with an \( p \) orbital from fluorine. 4. **Bond Length Consideration**: Because all the C-F bonds are formed using the same type of hybrid orbital (i.e., \( sp^3 \)), the bond lengths of all C-F bonds in the compound will be identical. This is due to the fact that identical hybridization leads to similar bond characteristics. 5. **Conclusion**: The correct statement regarding the compound \( F_3C-CF_2-CF_3 \) is that all the C-F bond lengths are identical. Therefore, the correct answer is option A. ### Final Answer: The correct statement is that all the bond lengths of C-F in \( F_3C-CF_2-CF_3 \) are identical. ---
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