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Formic acid is stronger acid than acetic...

Formic acid is stronger acid than acetic acid. Justify.

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`underset("Formic acid")(H-overset(O)overset(||)(C)-O-H)`
Methyl group in acetic acid has +I effect. It will increase the electron density on oxygen. As such release of `H^(+)` ion from acetic acid will be more difficult as compared to formic acid. Further +I effect of methyl group will destabilize the acetate ion relative to formate ion intensifying -ve charge on carboxylate ion. Hence `H^(+)` will be more difficult to relase from acetic acid than from formic acid. Hence formic acid is a stronger acid than acetic acid.
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BETTER CHOICE PUBLICATION-ORGANIC COMPOUND WITH FUNCTIONAL GROUP CONTANING OXYGEN-II-Question Bank (12.8 Chemical Reaction)
  1. How will you account for the acidic nature of carboxylic acid ?

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  2. Arrange the following in the increasing order of acidity : CHCl2 COOH,...

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  3. Formic acid is stronger acid than acetic acid. Justify.

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  4. Which acid would you expect to be stronger ? CH(3)COOH or HCOOH

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  5. Benzoic acid is stronger acid than acetic acid. Justify.

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  6. Ethanoic acid is weaker acid than benzoic acid.Why ?

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  7. p-Nitrobenzoic acid is a stronger acid than benzoic acid. Justify.

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  8. Although phenoxide ion has more number of resonating structures than c...

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  9. Why acetic-acid is a stronger acid than phenol ?

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  10. Which acid would you expect to be stronger:

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  11. Which acid would you expect to be stronger ?

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  12. Why chloroacetic acid is stronger acid than acetic acid ?

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  13. Fluoroacetic acid is stronger than acetic acid. Explain why ?

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  14. Write HVZ reaction.

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  15. Write short note on decarboxylation reaction.

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  16. Why trichloro acetic acid is stronger than acetic acid ?

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  17. Why dichloroacetic acid is stronger than monochloroacetic acid ?

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  18. Fluoroacetic acid is stronger than chloroacetic acid. Explain why ?

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  19. Convert the following : Acetic acid to acetaldehyde

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  20. Convert acetic acid to methylamine.

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