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Benzoic acid is stronger acid than aceti...

Benzoic acid is stronger acid than acetic acid. Justify.

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In benzoic acid, -COOH group is attached to `sp^(2)`-hybridised carbon atom of phenyl group while in ethanoic acid -COOH group is attached to `sp^(3)`-hybridised carbon atom of methyl group.

In general, `sp^(2)`-hybridised carbon atom is more electronegative than `sp^(3)`-hybridised carbon atom. More han electronegativity of the carbon to which -COOH group is attached, more is the acidic character due to electron withdrawing effect to hybridised carbon. Thus, benzoic acid with more electronegative C-atom is more acidic than ethanoic acid with less electronegative C-atom.
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BETTER CHOICE PUBLICATION-ORGANIC COMPOUND WITH FUNCTIONAL GROUP CONTANING OXYGEN-II-Question Bank (12.8 Chemical Reaction)
  1. Formic acid is stronger acid than acetic acid. Justify.

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  2. Which acid would you expect to be stronger ? CH(3)COOH or HCOOH

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  3. Benzoic acid is stronger acid than acetic acid. Justify.

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  4. Ethanoic acid is weaker acid than benzoic acid.Why ?

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  5. p-Nitrobenzoic acid is a stronger acid than benzoic acid. Justify.

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  6. Although phenoxide ion has more number of resonating structures than c...

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  7. Why acetic-acid is a stronger acid than phenol ?

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  8. Which acid would you expect to be stronger:

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  9. Which acid would you expect to be stronger ?

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  10. Why chloroacetic acid is stronger acid than acetic acid ?

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  11. Fluoroacetic acid is stronger than acetic acid. Explain why ?

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  12. Write HVZ reaction.

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  13. Write short note on decarboxylation reaction.

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  14. Why trichloro acetic acid is stronger than acetic acid ?

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  15. Why dichloroacetic acid is stronger than monochloroacetic acid ?

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  16. Fluoroacetic acid is stronger than chloroacetic acid. Explain why ?

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  17. Convert the following : Acetic acid to acetaldehyde

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  18. Convert acetic acid to methylamine.

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  19. Write the chemicat equations when acetic acid reacts with SOCl2, PCl3 ...

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  20. Write the chemicat equations when acetic acid reacts with SOCl2, PCl3 ...

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