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S(N)1 reaction is faster in...

`S_(N)1` reaction is faster in

A

`CH_(3) CH_(2) Cl`

B

C

`CH_(3)- overset(CH_(3)) overset(|) underset(CH_(3)) underset(|)( C) - Cl`

D

`CH_(3) - underset(CH_(3)) underset(|) underset(CH_(2))underset(|)(C )H - Cl`

Text Solution

Verified by Experts

The correct Answer is:
C

`S_(N^1)` mechanism proceeds through carbocation intermediate.
`CH_(3)-overset(CH_(3)) overset(|)underset(CH_(3))underset(|)(C )-Cl` provides stable carbocation intermediate because it has tertiary carbon
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Statement -1 : Rate of S_(N)1 reaction is faster than that of S_(N)2 reaction Statement -2 : S_(N)2 reaction is favoured by polar aprotic solvent Statement -3 : S_(N)1 reaction involves racemization

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Which alkyl halide from the following pair is (i) Chiral and (ii) undergoes S_(N)1 reaction faster ? (a) (CH_(3))_(3)CBr (b) CH_(3)CH_(2)CHBrCH_(3)

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ERRORLESS-GENERAL ORGANIC CHEMISTRY -NCERT BASED QUESTIONS (Organic Reactions and their Mechanism )
  1. The following reaction CH(3)-underset(CH(3))underset(|)overset(H)ove...

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  2. Which of the following statement is incorrect for biomolecular nucleop...

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  3. S(N)1 reaction is faster in

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  4. To which of the following four types does this reaction belong ?

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  5. The above reaction proceeds through

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  6. H(3)C- overset(CH(3))overset(|)underset(CH(3)) underset(|)( C) - Br + ...

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  7. The most common type of reaction in aromatic compounds is

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  8. Addition of HCl to vinyl chloride gives 1, 1-dichloroethane because of

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  9. The following compound will undergo electrophilic substitution more re...

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  10. Which of the following cannot undergo nucleophilic substitution under ...

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  11. Which of the following shows S(N^(1)) reaction most readily ?

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  12. Which gives nucleophilic addition reactions ?

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  13. Which one of the following species will be most reactive in S(N^(2)) r...

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  14. Arrange the following compounds in order of their decreasing reactivit...

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  15. Which of the following are correct chain isomers of butane ? (i) <im...

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  16. Which of the following undergoes nucleophilic substitution exclusively...

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  17. Hunsdiecker reaction involve free radical in intermediate steps.

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  18. Which give only monosubstituted product?

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  19. The species responsible for nitration is

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  20. Geometry of reaction intermediate in S(N^(1)) reaction is

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