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H(3)C- overset(CH(3))overset(|)underset(...

`H_(3)C- overset(CH_(3))overset(|)underset(CH_(3)) underset(|)( C) - Br + KOH (aq.) to H_(3) C - overset(CH_(3)) overset(|) underset(CH_(3)) underset(|)( C) - OH + KBr`
above reaction is

A

`S_(N^1)`

B

`S_(N^2)`

C

`E_(1)`

D

Both (a) and (b)

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AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of tert-butyl bromide with potassium hydroxide (KOH), we need to analyze the reaction mechanism and identify the type of reaction taking place. ### Step-by-Step Solution: 1. **Identify the Reactants and Products:** - The reactant is tert-butyl bromide (H₃C-C(CH₃)₂-Br). - The product is tert-butyl alcohol (H₃C-C(CH₃)₂-OH) along with KBr as a byproduct. 2. **Determine the Reaction Type:** - The reaction involves the substitution of a bromine atom (Br) with a hydroxyl group (OH). - Since tert-butyl bromide is a tertiary alkyl halide, it is likely to undergo an SN1 reaction due to the stability of the tertiary carbocation that can be formed. 3. **Mechanism of SN1 Reaction:** - **Step 1: Formation of Carbocation** - The bromine atom (Br) acts as a leaving group and departs from the tert-butyl bromide, forming a stable tertiary carbocation (H₃C-C(CH₃)₂⁺). - **Step 2: Nucleophilic Attack** - The hydroxide ion (OH⁻) from KOH attacks the carbocation, leading to the formation of tert-butyl alcohol (H₃C-C(CH₃)₂-OH). - **Byproduct Formation:** - The leaving bromine ion (Br⁻) combines with potassium (K⁺) from KOH to form KBr. 4. **Final Reaction Equation:** - The overall reaction can be summarized as: \[ \text{H}_3\text{C}-\overset{\text{(CH}_3)}{\underset{\text{(CH}_3)}{|}(C)-Br} + \text{KOH (aq)} \rightarrow \text{H}_3\text{C}-\overset{\text{(CH}_3)}{\underset{\text{(CH}_3)}{|}(C)-OH} + \text{KBr} \] 5. **Conclusion:** - The reaction is classified as an SN1 reaction, as it involves the formation of a carbocation intermediate and follows a two-step mechanism.

To solve the question regarding the reaction of tert-butyl bromide with potassium hydroxide (KOH), we need to analyze the reaction mechanism and identify the type of reaction taking place. ### Step-by-Step Solution: 1. **Identify the Reactants and Products:** - The reactant is tert-butyl bromide (H₃C-C(CH₃)₂-Br). - The product is tert-butyl alcohol (H₃C-C(CH₃)₂-OH) along with KBr as a byproduct. ...
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ERRORLESS-GENERAL ORGANIC CHEMISTRY -NCERT BASED QUESTIONS (Organic Reactions and their Mechanism )
  1. To which of the following four types does this reaction belong ?

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  2. The above reaction proceeds through

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  3. H(3)C- overset(CH(3))overset(|)underset(CH(3)) underset(|)( C) - Br + ...

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  4. The most common type of reaction in aromatic compounds is

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  5. Addition of HCl to vinyl chloride gives 1, 1-dichloroethane because of

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  6. The following compound will undergo electrophilic substitution more re...

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  7. Which of the following cannot undergo nucleophilic substitution under ...

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  8. Which of the following shows S(N^(1)) reaction most readily ?

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  9. Which gives nucleophilic addition reactions ?

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  10. Which one of the following species will be most reactive in S(N^(2)) r...

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  11. Arrange the following compounds in order of their decreasing reactivit...

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  12. Which of the following are correct chain isomers of butane ? (i) <im...

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  13. Which of the following undergoes nucleophilic substitution exclusively...

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  14. Hunsdiecker reaction involve free radical in intermediate steps.

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  15. Which give only monosubstituted product?

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  16. The species responsible for nitration is

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  17. Geometry of reaction intermediate in S(N^(1)) reaction is

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  18. Which of the following is most reactive toward nucleophilic substituti...

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  19. Neopentyl bromide undergoes dehydro halogenation to give alkene even t...

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  20. In electrophilic aromatic substitution reaction, the nitro group is me...

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