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Which of the following cannot undergo nu...

Which of the following cannot undergo nucleophilic substitution under ordinary conditions

A

Chlorobenzene

B

Tert-butylchloride

C

Isopropyl chloride

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
A
Chlorobenzene undergoes nucleophilic substitution under a drastic condition because due to resonance C-Cl bond acquire some double bond character as a result substitution of -Cl by nucleophile become difficult under ordinary condition.
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ERRORLESS-GENERAL ORGANIC CHEMISTRY -NCERT BASED QUESTIONS (Organic Reactions and their Mechanism )
  1. Addition of HCl to vinyl chloride gives 1, 1-dichloroethane because of

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  2. The following compound will undergo electrophilic substitution more re...

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  3. Which of the following cannot undergo nucleophilic substitution under ...

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  4. Which of the following shows S(N^(1)) reaction most readily ?

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  5. Which gives nucleophilic addition reactions ?

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  6. Which one of the following species will be most reactive in S(N^(2)) r...

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  7. Arrange the following compounds in order of their decreasing reactivit...

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  8. Which of the following are correct chain isomers of butane ? (i) <im...

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  9. Which of the following undergoes nucleophilic substitution exclusively...

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  10. Hunsdiecker reaction involve free radical in intermediate steps.

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  11. Which give only monosubstituted product?

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  12. The species responsible for nitration is

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  13. Geometry of reaction intermediate in S(N^(1)) reaction is

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  14. Which of the following is most reactive toward nucleophilic substituti...

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  15. Neopentyl bromide undergoes dehydro halogenation to give alkene even t...

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  16. In electrophilic aromatic substitution reaction, the nitro group is me...

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  17. Find the product of the given reaction

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  18. Match the following Column A to Column B

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  19. Dehydrohalogenation in presence of OH^(-) is correctly represented by

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  20. The enantiomeric pair among the following four structures

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