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Which will give chiral molecule ?...

Which will give chiral molecule ?

A

`CH_(3) COCl overset(LiAlH_(4))(to)`

B

`C_(2) H_(5)CHO overset(CH_(3) MgBr) underset(H^(+)// H_(2) O)(to)`

C

`(CH_(3))_(2) CH C_(2) H_(5) overset(Cu) (to)`

D

Text Solution

Verified by Experts

The correct Answer is:
B

`C_(2) H_(5) CHO overset(CH_(3)MgBr) underset(H^(+)//H_(2) O)(to) C_(2) H_(5) - overset(H)overset(|) underset(CH_(3))underset(|)( C^(**) - OH`
`C^(**)` -chiral carbon as all the four valencies are attached with different substituents or groups.
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ERRORLESS-GENERAL ORGANIC CHEMISTRY -NCERT BASED QUESTIONS (Structural and Stereo Isomerism )
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  2. The correct statement about the compounds A and B is

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  3. Which will give chiral molecule ?

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  4. The number of optical isomers of CH3CH(OH)CH(OH)CHO is :-

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  5. Consider the structures given below They are

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  6. Which one of the following compound is capcabel of existing in a meso ...

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  7. Consider the following representation They are

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  8. The number of chiral centres in D-(+)-glucose is

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  9. The number of racemic mixture obtained by optical isomers of 2, 3-dihy...

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  10. Which of the following compounds will exhibit optical isomerism ?

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  11. The R– isomers among the following are

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  12. The absolute configurations of the C(2) and C(3) atoms in the molecule...

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  13. While assigning R,S configuration the correct order of priority of gro...

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  14. How many enantiomer pairs are obtained by monochlorination of 2, 3-dim...

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  15. How many chiral stereoisomers can be drawn for 2 - bromo - 3 - chlorob...

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  16. In the reaction CH(3)CHO+HCNtoCH(3)CH(OH)CN a chiral centre is produce...

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  17. Which of the following is a chiral molecule ?

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  18. Glucose has optical isomers

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  19. Which of the following Fischer projection formula is same as D-Glycera...

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  20. How many optically active stereomers are possible for butane-2,3-diol

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