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Transition metal complex with highest va...

Transition metal complex with highest value of crystal field splitting `(Delta_0)` will be

A

`[Cr(H_2O)_6]^(3+)`

B

`[Mo(H_2O)_6]^(3+)`

C

`[Fe(H_2O)_6]^(3+)`

D

`[Os(H_2O)_6]^(3+)`

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To determine the transition metal complex with the highest value of crystal field splitting (Δ₀), we need to consider two main factors: the charge on the metal ion and the strength of the ligand. ### Step-by-Step Solution: 1. **Understanding Crystal Field Splitting (Δ₀)**: - Crystal field splitting energy (Δ₀) is the energy difference between the split d-orbitals in a transition metal complex. It is influenced by the metal ion's charge and the ligand's strength. 2. **Effect of Metal Ion Charge**: ...
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Define crystal field splitting energy ?

The complex that has highest crystal field splitting energy ( triangle ), is:

The complex having highest Delta value

Splitting energy (Delta_(0)) can usually be measured form the absorption spectra of the complex ions. In simple cases when light is absorbed by a complex ion, an electron in one of the lower energy orbitals is excited to one of the higher energy orbital. The energy corresponding to the frequency of absorbed light is equal to Delta_(0) . If value of Delta_(0) for the complex is in visible region, the complex is coloured and the value of Delta_(0) lies in ultraviolet or infrared region, the complex is colourless. For octahedral complexes, the cyrstal field stabilisation energy is given by CFSE= +[-0.4t_(2g)N+0.6e_(g)N_(1)]Delta_(0) Where N and N_(1) are number of electrons in t_(2g)" and "e_(g) orbitals respectively. The value of CFSE can be used for the correction of the experimental values of heats of hydration of divalent can be obtained by substracting the calculated CFSE values form the experimental values. The value of crystal field splitting (Delta_(0)) for [Ti(H_(2)O)_(6)^(3+) is 243 kj mol^(-1) . The crystal field stabilisation energy (CFSE) in this complex is : (in kj mol^(-1) )

Arrange following complex ions in increasing order of crystal field splitting energy (Delta_(0)) .

JEE MAINS PREVIOUS YEAR-JEE MAINS 2022-PART : CHEMISTRY
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