How can you explain higher stability of `BCI_(3)` as compared to `TICI_(3)`?

Explanation

Due to the poor shielding of the s-electrons of the valence shell (6s) by the 3d-,4d-,5d and 4f-electrons inert pair effect is maximum in Tl. As a result only `6 p^(1)` electrons participates in bond formation and contrast, due to the absence of d-and f-electrons , B does not show inert pair effect. In other words, all the three valence electrons (i.e, two 2s - and one 2p-) take part in bond formation and hence B shows an oxidation state of +3 and thus forms `BCl_(3)`. thus, `BCl_(3)` is more stable than `TlCl_(3)`.