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In which of the following all electronic...

In which of the following all electronic effects namely inductive, mesomeric and hyperconjugative effects are present?

A

B

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D

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The correct Answer is:
To determine which compound exhibits all three electronic effects—inductive, mesomeric, and hyperconjugative—we will analyze each option provided in the question. ### Step-by-Step Solution: 1. **Understanding Electronic Effects**: - **Inductive Effect**: This is the permanent effect due to the electronegativity difference between atoms, leading to a shift of electron density along a chain of atoms. - **Mesomeric Effect**: This refers to the delocalization of electrons through π-bonds or lone pairs, often seen in conjugated systems. - **Hyperconjugative Effect**: This is the interaction of σ-bonds (typically C-H or C-C) with an adjacent empty p-orbital or π-bond, which stabilizes the molecule. 2. **Analyzing Option 1**: - The compound in option 1 does not allow for the presence of all three effects. The shifting of π-bonds leads to an anti-aromatic system, which is unstable and does not exist. Hence, it cannot be the answer. 3. **Analyzing Option 2**: - This compound has a –M (minus mesomeric) group due to the presence of a carbonyl (C=O) group, which contributes to resonance. It also has an inductive effect due to electronegative atoms. However, it lacks hyperconjugation, as there are no adjacent σ-bonds interacting with π-bonds. Thus, this option is not the answer. 4. **Analyzing Option 3**: - Similar to option 2, this compound exhibits a –M effect due to the carbonyl group, and it shows inductive effects. However, it does not have hyperconjugation, as there are no suitable σ-bonds to contribute to this effect. Therefore, this option is also not the answer. 5. **Analyzing Option 4**: - In this compound, there is a +I (positive inductive) effect due to the presence of alkyl groups (like CH₃). It also exhibits resonance due to the presence of π-bonds, contributing to the mesomeric effect. Additionally, the presence of adjacent C-H bonds allows for hyperconjugation. Therefore, this option contains all three electronic effects. ### Conclusion: The correct answer is **Option 4**, as it is the only compound that exhibits inductive, mesomeric, and hyperconjugative effects.
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AAKASH INSTITUTE-ORGANIC CHEMISTRY: SOME BASIC PRINCIPLE AND TECHNIQUES-SECTION-B OBJECTIVE TYPE QUESTION (ONE OPTION IS CORRECT)
  1. Which of the following will have weakest indicated C-H bond?

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  2. Which of the following compounds will not dissolve in aqueous NaOH?

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  3. In which of the following all electronic effects namely inductive, mes...

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  4. Most acidic species among the following is

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  5. What is the index of hydrogen deficiencyd in the molecule C(12)H(17)NO...

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  6. Which of the following reactions will not generate a carbonion?

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  7. Which will have highest melting point?

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  8. Which of the following is the strongest base in water?

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  9. Which of the following is most acidic?

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  10. Isomers which can be interconverted through rotation around a single b...

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  11. In the given anion,-ve charge is delocalized on

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  12. The compounds are

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  13. Least stable carbocation among the following is

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  14. Which of the following compound will give blood red colour while doing...

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  15. The most stable free radical is

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  16. Which of the following group will have strongest electron donating mes...

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  17. Among the following the most stable carbocation

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  18. Most acidic species among the following is

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  19. Which of the following double bond in the given molecule is most react...

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  20. Which of the following hydrocarbon is most stable?

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