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Write the structure of the amide which g...

Write the structure of the amide which gives propanamine by Hofmann bromamide reaction?

Text Solution

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Propanamine contains three carbons. Hence, the amide molecules must contains four carbon atoms.
Structures of the amide with four carbon atoms are given below:
`CH_(3)-CH_(2)-CH_(2)-underset(O)underset(||)C-NH_(2)`
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Write Hofmann-bromamide reaction.

Write structures and IUPAC names of (i) the amide which gives propanamine by Hoffmann bromamide reaction. (ii) the amine produced by the Hoffmann degradation of benzamide.

Knowledge Check

  • In Hofmann's hypobromide reaction

    A
    The alkyl group in amide migrate to oxygen atom
    B
    The alkyl group in amide migrate to oxygen atom
    C
    There is a no migration of alkyl group of amide
    D
    Hydrogen atom is migrated to carbonyl oxgyen atom of amide

  • Product of this Hofmann bromamide reaction is

    A
    B
    C
    `Ph-CHO`
    D
    `Ph-CH_2-NH_2`

  • One of the following amides will not undergo Hofmann bromamide reaction:

    A
    `CH_(3)CONHCH_(3)`
    B
    `CH_(3)CH_(2)CONH_(2)`
    C
    `CH_(3)CONH_(2)`
    D
    `C_(6)H_(5)CONH_(2)`

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    Write structures and IUPAC names of (i) the amide which gives propanamine by Hoffmann bromamide reaction (ii) the alkyl halide used in Garbriel phthalimide synthesis to give ethanamine (iii) amine obtained by reduction of propanamide (iv) the amine produced by the Hoffmann degradation of benzamide.

    Write structure and IUPAC names of (i) The amide which gives propanamide by Hofmann bromamide reaction. (ii) the amine produce by the Hofmann degradation of benzamide.

    Product of this Hoffmann bromamide reaction is

    Write a short note on Hofmann's bromamide reaction.

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