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Delta(r) G^(@)= - RT " In K. For the sam...

`Delta_(r) G^(@)= - RT " In K. For the same reaction at the same temperature using " K_(c) and K_(p) " the values "Delta _(r)G^(@) " ` are found to be different . Why ?

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To understand why the values of ΔrG° (standard Gibbs free energy change) are found to be different when calculated using Kc (equilibrium constant in terms of concentration) and Kp (equilibrium constant in terms of partial pressure) for the same reaction at the same temperature, we can break down the explanation into several steps. ### Step-by-Step Solution: 1. **Understanding ΔrG° and its Relation to K**: The equation ΔrG° = -RT ln K relates the standard Gibbs free energy change (ΔrG°) to the equilibrium constant (K) of a reaction at a given temperature (T). Here, R is the universal gas constant and T is the temperature in Kelvin. 2. **Differentiating Between Kc and Kp**: ...
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It is planned to carry out the reaction: CaCO_(3)(g) hArr CaO(s) +CO_(2)(g) at 1273K and 1 bar pressure. Delta_(r)G^(Theta) = 176 kJ mol^(-1) and Delta_(r)S^(Theta) = 157.2 kJ mol^(-1) a. Is the reaction spontaneous at this temperature and pressure ? b. Calculate the value of i. K_(p) at 1273K for the reaction ii. partial pressure of CO_(2) at equilibrium

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Variation of equilibrium constan K with temperature is given by van't Hoff equation InK=(Delta_(r)S^(@))/R-(Delta_(r)H^(@))/(RT) for this equation, (Delta_(r)H^(@)) can be evaluated if equilibrium constans K_(1) and K_(2) at two temperature T_(1) and T_(2) are known. log(K_(2)/K_(1))=(Delta_(r)H^(@))/(2.303R)[1/T_(1)-1/T_(2)] For an isomerization X(g)hArrY(g) the temperature dependency of equilibrium cohnstant is given by : lnK=2-(1000)/T The value of Delta_(r)S^(@) at 300 K is :

The temperature at which K_(c) and K_(p) will have the same value for the equilibrium , N_(2) O_(4) (g) hArr 2 NO_(2) (g) is

Variation of equilibrium constan K with temperature is given by van't Hoff equation InK=(Delta_(r)S^(@))/R-(Delta_(r)H^(@))/(RT) for this equation, (Delta_(r)H^(@)) can be evaluated if equilibrium constans K_(1) and K_(2) at two temperature T_(1) and T_(2) are known. log(K_(2)/K_(1))=(Delta_(r)H^(@))/(2.303R)[1/T_(1)-1/T_(2)] Select the correct statement :

In the reaction 2NO(g) hArr N_(2)(g)+O_(2)(g) , the values of K_(c) and K_(p) are ……….. at a given temperature.

Delta G^(@) for a reaction is 46.06 kcal mol^(-) . K_(P) for the reaction at 300 K is

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