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10 mL solution of H(2)SO(4) and H(2)C(2)...

10 mL solution of `H_(2)SO_(4)` and `H_(2)C_(2)O_(4)` (oxalic acid), on titration with with 0.1 M KOH, required 20 " mL of " the base. 10 " mL of " the same solution on titration with `(M)/(300)K_(2)Cr_(2)O_(7)` required 50 " mL of " `K_(2)Cr_(2)O_(7)`.
Q. What should be the volume strength of `H_(2)Cr_(2)O_(7)`, if `H_(2)O_(2)` react with the same volume of `(M)/(300)K_(2)Cr_(2)O_(7)` solution.

A

5.6 V

B

0.56 V

C

11.2 V

D

1.12 V

Text Solution

Verified by Experts

The correct Answer is:
B

`m" Eq of "H_(2)O_(2)=m" Eq of "K_(2)Cr_(2)O_(7)`
`=(1 mEq)/(10mL)`
`=(1xx10^(-3)xx10^(3))/(10)EqL^(-1)=0.1N`
Volume the strength of `H_(2)O_(2)=0.1xx5.6=0.56V`
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10 mL solution of H_(2)SO_(4) and H_(2)C_(2)O_(4) (oxalic acid), on titration with with 0.1 M KOH, required 20 " mL of " the base. 10 " mL of " the same solution on titration with (M)/(300)K_(2)Cr_(2)O_(7) required 50 " mL of " K_(2)Cr_(2)O_(7) . Q. Strength of oxalic acid in the solution is:

10 mL solution of H_(2)SO_(4) and H_(2)C_(2)O_(4) (oxalic acid), on titration with with 0.1 M KOH, required 20 " mL of " the base. 10 " mL of " the same solution on titration with (M)/(300)K_(2)Cr_(2)O_(7) required 50 " mL of " K_(2)Cr_(2)O_(7) . Q. The strength of H_(2)SO_(4) is the solution is:

When H_(2)O_(2) is added to a acidified solution of K_(2)Cr_(2)O_(7) :

80 mL of M/24 K_(2)Cr_(2)O_(7) oxidises 22.4 mL H_(2)O_(2) solution. Find volume strength of H_(2)O_(2) solution.

What happens when H_(2)O_(2) is shaken with acidified K_(2)Cr_(2)O_(7) solution ?

Acidified solution of K_(2)Cr_(2)O_(7) on treatment with H_(2)O_(2) yields :

A mixture of K_(2)Cr_(2)O_(7) and conc. H_(2)SO_(4) forms

Acidic K_(2)Cr_(2)O_(7) reacts with H_(2)S to produce:

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