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If 20 " mL of " 0.1 M K(2)Cr(2)O(7) is r...

If 20 " mL of " 0.1 M `K_(2)Cr_(2)O_(7)` is required to titrate 10 " mL of " a liquid iron supplement, then the concentration of iron in the the the vitamin solution is

A

1.2 M

B

2.4 M

C

0.6 N

D

1.56 M

Text Solution

Verified by Experts

The correct Answer is:
A

`Cr_(2)O_(7)^(2-)+Fe^(2+)to2Cr^(3+)+Fe^(3+)`
(i). `6e^(-)+Cr_(2)O_(7)^(2-)to2Cr^(3+)(x=6)`
`(ii). `Fe^(2+)toFe^(3+)+e^(-)(x=1)`
`m" Eq of "Cr_(2)O_(7)^(2-)=m" Eq of "Fe^(2+)`
`20xx0.1xx6m" Eq of "10xxN`
`N=1.2`
`M=(N)/("n-factor")=(1.2)/(1)=1.2M`
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