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100 " mL of " 0.01 M KMnO(4) oxidised 10...

100 " mL of " 0.01 M `KMnO_(4)` oxidised 100 mL `H_(2)O_(2)` in acidic medium. The volume of same `KMnO_(4)` required in strong alkaline medium to oxidise 100 " mL of " same `H_(2)O_(2)` will be:

A

`(100)/(3)mL`

B

`(500)/(3)mL`

C

`(300)/(5)mL`

D

None

Text Solution

Verified by Experts

The correct Answer is:
B

`MnO_(4)^(ɵ)+5e^(-)toMn^(2+)` (acidic)
`MnO_(4)^(ɵ)+3e^(-)toMnO_(2)` (basic)
`100 mL H_(2)O_(2)-=100xx5N MnO_(4)^(ɵ)-=Vxx3NMnO_(2)`
`V=(500)/(3)mL`
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