Home
Class 11
CHEMISTRY
F(2) can be prepared by reacting hexfluo...

`F_(2)` can be prepared by reacting hexfluoro magnante (IV) with antimony pentafluoride as:
`K_(2)KnF_(6)+SbF_(5)overset(150^(@)C)toKSbF_(6)+MnF_(3)+F_(2)` ltBrgt The number of equivalent of `K_(2)MnF_(6)` requried to react completely with one " mol of "`SbF_(5)` in the given reaction is

A

`1.52`

B

`5.0`

C

`0.5`

D

`4.0`

Text Solution

Verified by Experts

The correct Answer is:
C


Adding equation (i), (ii) and (iii) we get
`underline(K_(2)MnF_(6)+2SbF_(5)to2KSbF_(6)+MnF_(3)+(1)/(2)F_(2))` ..(iv)
In equation (iii)
`e^(-)+overset(+4)(Mn)tooverset(+3)(Mn)` (n factor`=1`)
`F^(ɵ)to(1)/(2)F_(2)+e^(-)` (n-factor`=1`)
Therefore according to equation (iv)
`2 " mol of "SbF_(5)-=1" mol of "K_(2)MnF_(6)`
`-=1 " Eq of "K_(2)MnF_(6)`
`therefore 1 " mol of "SbF_(6)=(1)/(2)Eq=0.5" Eq of "K_(2)MnF_(6)`
Promotional Banner

Topper's Solved these Questions

  • STOICHIOMETRY

    CENGAGE CHEMISTRY|Exercise Exercises Assertion Reasoning|15 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY|Exercise Exercises Integer|16 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY|Exercise Exercises Multiple Correct|30 Videos
  • STATES OF MATTER

    CENGAGE CHEMISTRY|Exercise Exercises (Ture False)|25 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Archives (Subjective)|23 Videos

Similar Questions

Explore conceptually related problems

The number of moles of Fe_(2)O_(3) formed when 5.6 lit of O_(2) at STP reacts with 5.6g of Fe is

F_(2) is formed by reacting K_(2) MnF_(6) with

How many moles of H_2O_2 will be requried to react completely with 1.5 " mol of " K[Cr(OH)_4] (potassium tetrahydroxochromate (I)) in basic medium?

C_(6)H_(6)+HNO_(3) underset(355K)overset(Conc.H_(2)SO_(4))toX . In the given reaction X is

6xx10^(-3) mole K_(2)Cr_(2) C_(7) reacts completely with 9xx10^(-3) mole X^(n+) to give XO_(3)^(-) and Cr^(3+) . The value of n is :

The treatment of Me_(3)C-F with SbF_(5) in liquid SO_(2) would yield a

C_(6)H_(6) +A overset(AlCl_(3))(rarr) C_(6)H_(5)CONH_(2) A in the above reaction is :

For the reaction, 3Zn^(2+)+2K_(4)[Fe(CN)_(6)]rarr K_(2)Zn_(3)[Fe(CN)_(6)]_(2)+6K^(+) , what will be the equivalent weight of K_(4)[Fe(CN)_(6)] , if the molecular weight of K_(4)[Fe(CN)_(6)] is M ?

CENGAGE CHEMISTRY-STOICHIOMETRY-Exercises Single Correct
  1. RH(2) ( ion exchange resin) can replace Ca^(2+)d in hard water as. R...

    Text Solution

    |

  2. 100mL of H2O2 is oxidised by 100mL of 0.01M KMnO4 in acidic medium (Mn...

    Text Solution

    |

  3. F(2) can be prepared by reacting hexfluoro magnante (IV) with antimony...

    Text Solution

    |

  4. 3 " mol of "a mixture of FeSO(4) and Fe(2)(SO(4))(3) requried 100 " mL...

    Text Solution

    |

  5. 28 NO(3)^(-)+3As(2)S(3)+4H(2)O rarr 6AsO(4)^(3-)+28NO+9SO(4)^(2-)+H^(+...

    Text Solution

    |

  6. Which of the following reaction is oxidation- reduction?

    Text Solution

    |

  7. For the reaction M^(x+)+MnO(4)^(ө)rarrMO(3)^(ө)+Mn^(2+)+(1//2)O(2) ...

    Text Solution

    |

  8. In the mixture of (NaHCO(3)+Na(2)CO(3)) volume of HCl required is x mL...

    Text Solution

    |

  9. Which of the following does not represent redox reaction?

    Text Solution

    |

  10. 10 " mL of " NaHC(2)O(4) is oxidised by 10 " mL of " 0.02 M MnO(4)^(ɵ)...

    Text Solution

    |

  11. 1 mole of ferric oxalate is oxidised by x mole of MnO(4)^(-) in acidic...

    Text Solution

    |

  12. 2 "mole" N(2) and 3 "mole" H(2) gas are allowed to react in a 20 L fla...

    Text Solution

    |

  13. K(2)Cr(2)O(7) is obtained in the following steps: 2FeCrO(4)+2Na(2)CO...

    Text Solution

    |

  14. 40 mL 0.05 M solution of sodium sesquicarbonate dehydrate (Na(2)CO(3)....

    Text Solution

    |

  15. What volume of 0.05 M K(2)Cr(2)O(7) in acidic medium is needed for com...

    Text Solution

    |

  16. MnO(4)^(2-) (1 mole) in neutral aqueous medium is disproportionate to

    Text Solution

    |

  17. If equal volumes of 0.1 M KMnO(4) and 0.1 M K(2)Cr(2)O(7) solutions ar...

    Text Solution

    |

  18. 100mL of 1M KMnO(4) oxidised 100mL of H(2)O(2) in acidic medium ( when...

    Text Solution

    |

  19. The volume strength of 1.5 N H2O2 solution is

    Text Solution

    |

  20. The equivalent weight of MnSO(4) is half its molecular weight when it ...

    Text Solution

    |