Home
Class 12
CHEMISTRY
RCH = CH(2) adds on water in the presenc...

`RCH = CH_(2)` adds on water in the presence of dilute sulphuric acid or phosphoric acid to form

A

`R – CH(OH)–CH_(3)`

B

`R – CH_(2) – CH_(2)OH`

C

`R – CHOH – CH_(2)– CH_(2)– CHOH –R`

D

`R-underset(OH)underset(|)(CH)-underset(OH)underset(|)(CH_(2))`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question about the reaction of RCH=CH₂ with water in the presence of dilute sulfuric acid or phosphoric acid, we will follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactant is an alkene, RCH=CH₂, which has a double bond between the carbon atoms. **Hint**: Recognize that alkenes are reactive due to their double bonds. 2. **Reaction Conditions**: The reaction occurs in the presence of dilute sulfuric acid (H₂SO₄) or phosphoric acid (H₃PO₄). These acids will protonate the alkene. **Hint**: Understand that acids can donate protons (H⁺) which can initiate the reaction. 3. **Protonation of the Alkene**: The double bond in the alkene acts as a nucleophile and attacks the proton (H⁺) from the acid. This leads to the formation of a carbocation intermediate. **Hint**: Remember that the more stable carbocation will form preferentially. 4. **Formation of Carbocation**: The protonation occurs at the less substituted carbon (if R is a larger group), leading to the formation of a more stable carbocation at the other carbon. **Hint**: Stability of carbocations is key; tertiary > secondary > primary. 5. **Nucleophilic Attack by Water**: Water (H₂O) acts as a nucleophile and attacks the carbocation, leading to the formation of an alcohol. **Hint**: Water can donate a pair of electrons to form a bond with the carbocation. 6. **Deprotonation**: The final step involves the deprotonation of the oxonium ion (the intermediate formed after water attacks the carbocation) to yield the final alcohol product. **Hint**: Look for the removal of a proton (H⁺) to stabilize the alcohol. 7. **Final Product**: The final product is R-CHOH-CH₃, which is a secondary alcohol. **Hint**: Identify the structure of the product to confirm it is a secondary alcohol. ### Final Answer: The product formed from the reaction of RCH=CH₂ with water in the presence of dilute sulfuric acid or phosphoric acid is R-CHOH-CH₃, a secondary alcohol.
Promotional Banner

Topper's Solved these Questions

  • HYDROCARBON

    MOTION|Exercise Exercise - 2 (Level-I)|29 Videos
  • HYDROCARBON

    MOTION|Exercise Exercise - 3|14 Videos
  • HYDROCARBON

    MOTION|Exercise QUESTIONS|6 Videos
  • GRIGNARD REAGENT

    MOTION|Exercise EXERCISE-2|16 Videos
  • IONIC EQUILIBRUIM

    MOTION|Exercise Exercise -4 (Level -II)|14 Videos

Similar Questions

Explore conceptually related problems

The reaction between zinc and dilute sulphuric acid is a

Hydrolysis of an ester in the presence of a dilute acid is known as saponification.

How many electrons are accepted when KMn0_(4) acts as an oxidising agent in the presence of dilute sulphuric acid?

Acid rain is due to the presence of oxides of sulphur in air.

MOTION-HYDROCARBON -Exercise - 1
  1. CH(3)-underset(CH(3))underset(|)(C)H-CH=CH(2)+HBr rarr (product) which...

    Text Solution

    |

  2. The catalyst used in kharash reaction, is -

    Text Solution

    |

  3. RCH = CH(2) adds on water in the presence of dilute sulphuric acid or ...

    Text Solution

    |

  4. Two jars A and B are filled with hydrocarbons. Br2 in C Cl(4) is added...

    Text Solution

    |

  5. Which of the following characteristics apply both to ethene and ethyne...

    Text Solution

    |

  6. Baeyer's reagent is:

    Text Solution

    |

  7. Ozonolysis of 2-methylbut-2-ene yields -

    Text Solution

    |

  8. Which set of products is expected on reductive ozonolysis of the follo...

    Text Solution

    |

  9. Unbranched alkenes on ozonolysis give -

    Text Solution

    |

  10. Ethylene forms ethylene chlorohydrin by the action of -

    Text Solution

    |

  11. 3-Methyl-2-pentene on reaction with HOCl gives-

    Text Solution

    |

  12. Alkene overset(B(2)H(6))tooverset(H(2)O(2)//OH^(-))to2^(@) alcohol the...

    Text Solution

    |

  13. Propene, CH(3) – CH = CH(2) can be converted into 1– propanol by oxida...

    Text Solution

    |

  14. Isobutylene on hydroboration followed by reaction with H(2)O(2) /OH^(–...

    Text Solution

    |

  15. Which alkene on heating with hot and conc. KMnO(4) solution gives acet...

    Text Solution

    |

  16. Which one of the following formula correctly represents the organic co...

    Text Solution

    |

  17. For preparing R–C-=CH, from Grignard’s reagent we take -

    Text Solution

    |

  18. CHCl(3) + CH(3)C Cl(3) + 6Ag rarr A + 6AgCl. The compound A is -

    Text Solution

    |

  19. Propyne is formed by heating 1,2-dibromopropane with -

    Text Solution

    |

  20. Acetylenic hydrocarbons are acidic because

    Text Solution

    |