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In the reaction CH(3)CH(2)C Cl(2)CH(3)...

In the reaction
`CH_(3)CH_(2)C Cl_(2)CH_(3)overset(x)rarrCH_(3)C-=C CH_(3)` the reagent X is -

A

`KOH // C_(2)H_(5)OH`

B

Zn

C

`HCl//H_(2)O`

D

Na

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The correct Answer is:
To determine the reagent \( X \) in the reaction \[ \text{CH}_3\text{CH}_2\text{CCl}_2\text{CH}_3 \xrightarrow{x} \text{CH}_3\text{C} \equiv \text{C}\text{CH}_3 \] we need to analyze the transformation occurring in the reaction. ### Step-by-Step Solution: 1. **Identify the Starting Material**: The starting compound is 1,2-dichlorobutane (CH₃CH₂CCl₂CH₃), which contains two chlorine atoms on adjacent carbons. This structure is known as a geminal dihalide. 2. **Recognize the Target Compound**: The target compound is 2-butyne (CH₃C≡CCH₃), which is an alkyne. The conversion from a geminal dihalide to an alkyne typically involves the elimination of two halogen atoms and two hydrogen atoms. 3. **Determine the Type of Reaction**: The reaction is an elimination reaction, specifically an E2 elimination, where a strong base removes a proton (H⁺) and a leaving group (Cl⁻) simultaneously. 4. **Identify the Reagent**: For the elimination to occur, a strong base is required. In this case, potassium hydroxide (KOH) is a suitable reagent. It can abstract the hydrogen atoms adjacent to the carbon atoms bearing the chlorine atoms. 5. **Write the Reaction Mechanism**: - The base (KOH) abstracts a proton from the carbon adjacent to the carbon with the first Cl atom, forming a double bond and releasing one Cl atom. - The base then abstracts another proton from the adjacent carbon, leading to the formation of a triple bond and releasing the second Cl atom. 6. **Final Reaction**: The overall transformation can be summarized as: \[ \text{CH}_3\text{CH}_2\text{CCl}_2\text{CH}_3 \xrightarrow{\text{KOH}} \text{CH}_3\text{C} \equiv \text{C}\text{CH}_3 \] ### Conclusion: The reagent \( X \) is **KOH** (potassium hydroxide). ---
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MOTION-HYDROCARBON -Exercise - 1
  1. Which can yield acetylene in single step

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  2. For preparing methyl acetylene, we take -

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  3. In the reaction CH(3)CH(2)C Cl(2)CH(3)overset(x)rarrCH(3)C-=C CH(3) ...

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  4. CH-=C-COOHoverset(HgSO(4) // H(2)SOH(4))rarr product (A) is

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  5. Ethyne adds on HCl to first give a-

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  6. The catalyst required for the reaction HC-=CH+dil.H(2)SO(4)overset("...

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  7. Hydration of propyne gives -

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  8. By the addition of CO and H(2)O on ethyne, the following is obtained -

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  9. Westrosol is a solvent & it is prepared by -

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  10. The reaction HC-=CHrarr CHCl(2)CHO takes place in

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  11. By the action of hydrobromic acid on ethyne we get -

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  12. Reaction of alkenes and alkynes with hypochlorous acid is called -

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  13. The alkyne which gives pyruvic acid (CH(3)COCOOH) on oxidation with al...

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  14. An alkyne which gives two moles of acetic acid on ozonolysis is -

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  15. An alkyne C(7)H(12) when reacted with alkaline KMnO(4) followed by aci...

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  16. Which one of these will react with sodium metal-

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  17. A compound (C(5)H(8)) reacts with ammoniacal AgNO(3) to give a white p...

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  18. Which one of the following compounds will give white preciptate with t...

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  19. A mixture of CH(4),C(2)H(4) and C(2)H(2) gases are passed through a Wo...

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  20. A hydrocarbon, ‘X’(C(3)H(4)) decolourise bromine in carbon tetrachlori...

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