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Westrosol is a solvent & it is prepared ...

Westrosol is a solvent & it is prepared by -

A

`CH-=CH+2Cl_(2)`

B

`CH-=CH+2HCl&` then `Ca(OH)_(2)`

C

`CH-=CH+2Cl_(2)&Ca(OH)_(2)`

D

none of these

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The correct Answer is:
To prepare Westrosol, we need to follow a series of chemical reactions starting from acetylene (ethyne). Here’s a step-by-step breakdown of the preparation process: ### Step 1: Starting Material - **Identify the starting material**: We begin with acetylene (C₂H₂), which is a simple alkyne with a triple bond between the two carbon atoms. ### Step 2: Chlorination of Acetylene - **Add chlorine**: We react acetylene with chlorine (Cl₂) in the presence of carbon tetrachloride (CCl₄) as a solvent. This reaction introduces chlorine atoms into the molecule. **Reaction**: \[ C_2H_2 + Cl_2 \xrightarrow{CCl_4} 1,2-Dichloroethene (C_2H_2Cl_2) \] ### Step 3: Further Chlorination - **Chlorinate again**: The product from Step 2 (1,2-dichloroethene) is then subjected to further chlorination. We add another molecule of chlorine to this compound. **Reaction**: \[ C_2H_2Cl_2 + Cl_2 \rightarrow 1,1,2,2-Tetrachloroethane (C_2H_2Cl_4) \] ### Step 4: Dehydrochlorination - **Remove HCl**: To convert tetrachloroethane to Westrosol, we need to remove one of the chlorine atoms. This is done by treating the compound with a base, such as calcium hydroxide (Ca(OH)₂), which acts to deprotonate the compound and eliminate HCl. **Reaction**: \[ C_2H_2Cl_4 + Ca(OH)_2 \rightarrow C_2HCl_3 + HCl \] ### Step 5: Final Product - **Formation of Westrosol**: The final product after the elimination of HCl is Westrosol, which is identified as 1,1,2-trichloroethene (C₂HCl₃). ### Summary of the Preparation 1. Start with acetylene (C₂H₂). 2. Chlorinate to form 1,2-dichloroethene (C₂H₂Cl₂). 3. Chlorinate again to form 1,1,2,2-tetrachloroethane (C₂H₂Cl₄). 4. Treat with calcium hydroxide to remove HCl and form Westrosol (C₂HCl₃).
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MOTION-HYDROCARBON -Exercise - 1
  1. Which can yield acetylene in single step

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  2. For preparing methyl acetylene, we take -

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  3. In the reaction CH(3)CH(2)C Cl(2)CH(3)overset(x)rarrCH(3)C-=C CH(3) ...

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  4. CH-=C-COOHoverset(HgSO(4) // H(2)SOH(4))rarr product (A) is

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  5. Ethyne adds on HCl to first give a-

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  6. The catalyst required for the reaction HC-=CH+dil.H(2)SO(4)overset("...

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  7. Hydration of propyne gives -

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  8. By the addition of CO and H(2)O on ethyne, the following is obtained -

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  9. Westrosol is a solvent & it is prepared by -

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  10. The reaction HC-=CHrarr CHCl(2)CHO takes place in

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  11. By the action of hydrobromic acid on ethyne we get -

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  12. Reaction of alkenes and alkynes with hypochlorous acid is called -

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  13. The alkyne which gives pyruvic acid (CH(3)COCOOH) on oxidation with al...

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  14. An alkyne which gives two moles of acetic acid on ozonolysis is -

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  15. An alkyne C(7)H(12) when reacted with alkaline KMnO(4) followed by aci...

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  16. Which one of these will react with sodium metal-

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  17. A compound (C(5)H(8)) reacts with ammoniacal AgNO(3) to give a white p...

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  18. Which one of the following compounds will give white preciptate with t...

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  19. A mixture of CH(4),C(2)H(4) and C(2)H(2) gases are passed through a Wo...

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  20. A hydrocarbon, ‘X’(C(3)H(4)) decolourise bromine in carbon tetrachlori...

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