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The reaction HC-=CHrarr CHCl(2)CHO takes...

The reaction `HC-=CHrarr CHCl_(2)CHO` takes place in

A

`HC-=CHoverset(HOCl)rarr`

B

`HC-=CHunderset("peroxide")overset(HCl)rarr`

C

`HC-=CHoverset(Cl_(2))rarr`

D

`HC-=CHunderset("Oxidizing agent")overset(Cl_(2))rarr`

Text Solution

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The correct Answer is:
To determine the reaction that converts acetylene (HC≡CH) to the compound CHCl₂CHO, we need to analyze the reagents that can facilitate this transformation. ### Step-by-Step Solution: 1. **Identify the Starting Material**: The starting material is acetylene, represented as HC≡CH. This is a simple alkyne with a triple bond between two carbon atoms. 2. **Identify the Target Compound**: The target compound is CHCl₂CHO. This compound contains a carbonyl group (C=O) and two chlorine atoms (Cl) attached to one of the carbon atoms. 3. **Consider Possible Reagents**: To convert acetylene to the desired product, we need to consider reagents that can add chlorine and facilitate the formation of a carbonyl group. 4. **Use of HOCl (Hypochlorous Acid)**: The reagent HOCl can be used for this reaction. HOCl dissociates into OH⁻ and Cl⁺. The hydroxyl group (OH) acts as a nucleophile, while the chlorine (Cl) acts as an electrophile. 5. **First Reaction Step**: When acetylene reacts with HOCl, the nucleophile (OH) attacks the electrophile (Cl). This results in the formation of a dichloro compound. The reaction can be visualized as follows: - HC≡CH + HOCl → CHCl₂C(OH) (dichloro alcohol) 6. **Second Reaction Step**: The dichloro alcohol can undergo dehydration (loss of water) to form a carbonyl compound. The reaction can be represented as: - CHCl₂C(OH) → CHCl₂CHO + H₂O 7. **Conclusion**: The reaction of acetylene with HOCl leads to the formation of CHCl₂CHO through the intermediate dichloro alcohol. Therefore, the correct reagent for this transformation is HOCl. ### Final Answer: The reaction `HC≡CH → CHCl₂CHO` takes place in the presence of **HOCl (Hypochlorous Acid)**.
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MOTION-HYDROCARBON -Exercise - 1
  1. Which can yield acetylene in single step

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  2. For preparing methyl acetylene, we take -

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  3. In the reaction CH(3)CH(2)C Cl(2)CH(3)overset(x)rarrCH(3)C-=C CH(3) ...

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  4. CH-=C-COOHoverset(HgSO(4) // H(2)SOH(4))rarr product (A) is

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  5. Ethyne adds on HCl to first give a-

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  6. The catalyst required for the reaction HC-=CH+dil.H(2)SO(4)overset("...

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  7. Hydration of propyne gives -

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  8. By the addition of CO and H(2)O on ethyne, the following is obtained -

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  9. Westrosol is a solvent & it is prepared by -

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  10. The reaction HC-=CHrarr CHCl(2)CHO takes place in

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  11. By the action of hydrobromic acid on ethyne we get -

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  12. Reaction of alkenes and alkynes with hypochlorous acid is called -

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  13. The alkyne which gives pyruvic acid (CH(3)COCOOH) on oxidation with al...

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  14. An alkyne which gives two moles of acetic acid on ozonolysis is -

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  15. An alkyne C(7)H(12) when reacted with alkaline KMnO(4) followed by aci...

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  16. Which one of these will react with sodium metal-

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  17. A compound (C(5)H(8)) reacts with ammoniacal AgNO(3) to give a white p...

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  18. Which one of the following compounds will give white preciptate with t...

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  19. A mixture of CH(4),C(2)H(4) and C(2)H(2) gases are passed through a Wo...

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  20. A hydrocarbon, ‘X’(C(3)H(4)) decolourise bromine in carbon tetrachlori...

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