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CH(3)-C-=C-CH(3)underset(Pd-BaSO(4))over...

`CH_(3)-C-=C-CH_(3)underset(Pd-BaSO_(4))overset(H_(2))rarr(A)`
`overset("cold. "KMnO_(4))rarr(B)`. Compound (B) is :

A

Meso

B

Recemic mixture

C

Diastereomers

D

All

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AI Generated Solution

The correct Answer is:
To solve the given problem step by step, let's break down the reactions involved: ### Step 1: Identify the starting compound The starting compound is 1-butyne, represented as \( CH_3-C \equiv C-CH_3 \). ### Step 2: Reaction with Hydrogen in the presence of Pd-BaSO4 The reaction of 1-butyne with hydrogen gas (\( H_2 \)) in the presence of palladium on barium sulfate (Pd-BaSO4) is known as the Rosenmund reduction. This reaction reduces the triple bond (alkyne) to a double bond (alkene) and specifically produces a cis-alkene. Thus, the product \( A \) formed is **cis-2-butene**: \[ CH_3-C \equiv C-CH_3 \xrightarrow{H_2, Pd-BaSO_4} \text{cis-}CH_3-CH=CH-CH_3 \] ### Step 3: Reaction with Cold KMnO4 Next, the compound \( A \) (cis-2-butene) reacts with cold potassium permanganate (\( KMnO_4 \)). This reagent is used for syn-dihydroxylation of alkenes, meaning it adds hydroxyl groups (\( OH \)) across the double bond in a syn fashion (both \( OH \) groups are added to the same side). The reaction can be represented as: \[ \text{cis-}CH_3-CH=CH-CH_3 \xrightarrow{cold \, KMnO_4} \text{meso-2,3-butanediol} \] ### Step 4: Identify the final product (B) The final product \( B \) is **meso-2,3-butanediol**. This compound has a plane of symmetry, making it a meso compound. ### Conclusion Thus, the compound \( B \) is **meso-2,3-butanediol**. ---
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MOTION-HYDROCARBON -Exercise - 2 (Level-I)
  1. Me-underset(Et)underset(|)(CH)-CH=CH-Phoverset(HCl)rarrW,W is

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  2. 1-Penten-4-yne reacts with 1 mol bromine at -80°C to produce :

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  3. Which is expected to react most readily with bromine

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  4. CH(3)-C-=C-CH(3)underset(Pd-BaSO(4))overset(H(2))rarr(A) overset("co...

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  5. Which of the following will decolourise alkaline KMnO(4)?

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  6. CH(3)-C-=C-CH(3)underset(Pd-BaSO(4))overset(H(2))rarr (A) underset(C...

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  7. Ozonolysis of CH(3)—CH=C=CH(2) will give

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  8. O-xylene on ozonolysis will give:

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  9. (A)C(4)H(10)Ounderset(Delta)overset("Conc."H(2)SO(4))rarrCH(3)-overset...

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  10. In which of the following reaction formation of racemic mixture.

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  11. underset((a))CH(3)-C-=C-underset((b))(CH(2)-CH)=CH-CH(2)-underset((c))...

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  12. CH(3)-underset((a))(C)-=C-CH(2)-CHunderset((b))(=)CH(2) Reactivity t...

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  13. Which of the following will produce aromatic product.

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  14. Find out number of dimerize products obtain by following reaction. H...

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  15. How many total organic products are obtained in following reaction. ...

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  16. Match the column (4 × 5) (Reaction) (Possible major product) x(1...

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  17. Benzylchloride (C(6)H(5)CH(2)Cl) can be prepared from toluene by chlo...

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  18. An alkene on ozonolysis yields only ethanal. There is an isomer of the...

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  19. CH(2)= CHCH(2)CH=CH(2) overset(NBS)rarr X( Major ),(X) is :

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  20. Which of the following reactants will give same product with HBr in p...

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