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What is a heteroleptic complex ?...

What is a heteroleptic complex ?

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Complex in which metal ion /atom is bound to more than one kind of donor groups.
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The complex [Co(NH_(3))_(6)]^(3+) is an inner orbital complex whereas the [CoF_(6)]^(3-) is an outer orbital complex. The number of unpaired electrons in these two complexes are respectively :

OSWAAL PUBLICATION-CO-ORDINATION COMPOUNDS-TOPIC-1 (CO-ORDINATION COMPOUNDS AND THEIR PROPERTIES, IUPAC NOMENCLATURE OF MONONUCLEAR CO-ORDINATION COMPOUNDS (Long Answer Type Question-I)
  1. Mention the geometry, magnetic property and type of hybridization in [...

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  2. Give differences between [NiCl4]^(2-) and [NI(CN)4]^(2-) with respect ...

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  3. What is a heteroleptic complex ?

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  4. Give the IUPAC name of K3 [Cr(C2 O4)3]

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  5. When a linkage isomerism is possible for co-ordination compounds ?

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  6. Give the IUPAC name of [CoCl2 (NH3)4] Cl. Draw cis and trans isomers ...

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  7. (a) What is coordination isomerism? Give an example.

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  8. Write the IUPAC name of the complex: [Ag (NH3)2] [Ag(CN)2] .

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  9. For [Co (en)3] Cl3 : Give the IUPAC name.

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  10. For (Co(en)(3))Cl(3). Give the coordination number of the central me...

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  11. For [Co (en)3] Cl3 : What type of stereoisomerism does it exhibit ?

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  12. For the given complex [Co(NH(3))(5)Br]SO(4), write the IUPAC name and ...

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  13. Which set of d-orbitals of a metal atom/ion experience more repulsion ...

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  14. Give the IUPAC name of [Ti(H(2)O)(6)]^(3+). Draw cis and trans isomers...

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  15. Mention the geometry and magentic property of tetracarbonylnickel comp...

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  16. [Fe(CN)6]^(4-) and Fe(H2 O)6]^(2+) are different colours in dilute sol...

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  17. The oxidation number of cobalt in K[Co(CO)4] is : (i) + 1 (ii) + 3 (ii...

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  18. Write the IUPAC name of the complex [Cr(NH3)4 Cl2] Cl.

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  19. What type of isomerism is exhibited by the complex [Co(en)3]^(3+) ? (...

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  20. Why is [NiCl4]^(2-) paramagnetic but [Ni(CO)4] is diamagnetic ? (...

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