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Which of the following compounds will gi...

Which of the following compounds will give ethyl alochol on reduction with `LiAlH_4` ?

A

`(CH_3 CO)_2 O`

B

`CH_3 COCl`

C

`CH_3 CONH_2`

D

`CH_3 COOC_2 H_5`

Text Solution

Verified by Experts

The correct Answer is:
A, B, D
a) Anhydride reduced by `LiAlH_4` one mole of anhydride gives two moles of primary Alcohol
`H_3 C - overset(O)overset(||)C- O-overset(O)overset(||)C-CH_3 overset(LiAlH_4)to 2H_3 C - CH-2 -OH`
b) `H_3C -overset(O)overset(||)C-Cl overset(LiAlH_4)to H_3 C -CH_2 OH`
c) `H_3 C-overset(O)overset(||)C-NH_2 underset("Na in Alcohol")overset(LiAlH_4)to 2H_3 C - CH_2 Oh`
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