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Me3SiCl is used during polymerisation of...

`Me_3SiCl` is used during polymerisation of organo silicones because

A

chain length of organo silicone polymers can be controlled by adding `Me_(3)SiCl`

B

`Me_(3)SiCl` blocks the end terminal of silicone polymer

C

`Me_(3)SiCl` improves the quality and yield of the polymer

D

`Me_(3)SiCl` acts as a catalyst during polymerisation

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding why Me₃SiCl is used during the polymerization of organosilicones, we can break down the reasoning step by step. ### Step-by-Step Solution: 1. **Understanding Organosilicones**: - Organosilicones are polymers that consist of silicon (Si) and oxygen (O) atoms, often with organic groups attached. They can form long chains, which can be represented as Si-O-Si-O... with organic groups like CH₃ attached to the silicon atoms. **Hint**: Remember that organosilicones are characterized by their silicon-oxygen backbone and organic side groups. 2. **Role of Me₃SiCl**: - Me₃SiCl (trimethylsilyl chloride) is a compound that can be used to modify the ends of these silicon chains. When added to the polymerization process, it can help control the chain length of the resulting polymer. **Hint**: Think about how modifying the ends of a polymer chain can affect its properties and behavior. 3. **Chain Termination**: - The addition of Me₃SiCl can terminate the growing polymer chain. If the chain ends with an OH group, it can continue to grow. However, if it is terminated with a trimethylsilyl group (from Me₃SiCl), the chain cannot grow any further. **Hint**: Consider how chain termination affects the overall structure and length of the polymer. 4. **Hydrolysis Reaction**: - When Me₃SiCl is hydrolyzed, it replaces the chlorine atom with an OH group, effectively terminating the polymer chain. This reaction can be represented as: \[ \text{Si(CH}_3\text{)}_3\text{Cl} + \text{H}_2\text{O} \rightarrow \text{Si(CH}_3\text{)}_3\text{OH} + \text{HCl} \] **Hint**: Focus on the chemical reaction that allows for the termination of the polymer chain. 5. **Evaluating Options**: - Based on the above understanding, we can evaluate the options given in the question: - **A**: Chain length of organosilicon polymer is controlled by adding Me₃SiCl. (Correct) - **B**: Me₃SiCl blocks the N terminal of silicon polymer. (Correct, as it terminates the chain) - **C**: Me₃SiCl improves the quality and yield of the polymer. (Incorrect, it terminates the chain) - **D**: Me₃SiCl acts as a catalyst during polymerization. (Incorrect, it does not catalyze but terminates) **Hint**: Analyze each option in the context of the role of Me₃SiCl in polymerization. 6. **Conclusion**: - The correct answers are options A and B, as Me₃SiCl is used to control the chain length and block the terminal ends of the silicon polymer. ### Final Answer: Me₃SiCl is used during polymerization of organosilicones because it controls the chain length and blocks the terminal ends of the silicon polymer.

To solve the question regarding why Me₃SiCl is used during the polymerization of organosilicones, we can break down the reasoning step by step. ### Step-by-Step Solution: 1. **Understanding Organosilicones**: - Organosilicones are polymers that consist of silicon (Si) and oxygen (O) atoms, often with organic groups attached. They can form long chains, which can be represented as Si-O-Si-O... with organic groups like CH₃ attached to the silicon atoms. **Hint**: Remember that organosilicones are characterized by their silicon-oxygen backbone and organic side groups. ...
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