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Which of the following statements are co...

Which of the following statements are correct ?

A

Fullerences have dangling bonds

B

Fullerences are cage-like molecules

C

Graphite is thermodynamically most stable allotrope of carbon

D

Graphite is slippery and hard and therefore used as a dry lubricant in machines.

Text Solution

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The correct Answer is:
To determine which statements about fullerenes and graphite are correct, we will analyze each statement one by one. ### Step-by-Step Solution: 1. **Statement A: Fullerenes have dangling bonds.** - Fullerenes are allotropes of carbon, specifically C60, which have a cage-like structure resembling a football. In this structure, the carbon atoms are bonded in a way that does not leave any unbonded or "dangling" bonds. Therefore, this statement is **incorrect**. 2. **Statement B: Fullerenes are cage-like molecules.** - As mentioned, fullerenes have a distinct cage-like structure formed by a combination of hexagonal and pentagonal arrangements of carbon atoms. This characteristic is a defining feature of fullerenes. Therefore, this statement is **correct**. 3. **Statement C: Graphite is the thermodynamically most stable allotrope of carbon.** - Under standard conditions, graphite is indeed the most stable allotrope of carbon. This is well-established in thermodynamic studies. Therefore, this statement is **correct**. 4. **Statement D: Graphite is slippery and hard, and therefore used as a dry lubricant in machines.** - While it is true that graphite is slippery and is used as a dry lubricant, it is **not hard**; in fact, graphite is soft. The hardest allotrope of carbon is diamond. Therefore, this statement is **incorrect**. ### Conclusion: From the analysis, we conclude that: - **Statement A**: Incorrect - **Statement B**: Correct - **Statement C**: Correct - **Statement D**: Incorrect Thus, the correct statements are **B and C**.

To determine which statements about fullerenes and graphite are correct, we will analyze each statement one by one. ### Step-by-Step Solution: 1. **Statement A: Fullerenes have dangling bonds.** - Fullerenes are allotropes of carbon, specifically C60, which have a cage-like structure resembling a football. In this structure, the carbon atoms are bonded in a way that does not leave any unbonded or "dangling" bonds. Therefore, this statement is **incorrect**. 2. **Statement B: Fullerenes are cage-like molecules.** ...
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