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The reaction of sulphur in alkaline medi...

The reaction of sulphur in alkaline medium is the below:
`S_(8(s))+aOH_(aq)^(-)rarrbS_((aq))^(2-)+cS_2O_(3" "aq)^(2-)+dH_2O_((l))`
The values of 'a' is `"____"`. (Integer answer)

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To solve the problem, we need to balance the given chemical reaction involving sulfur in an alkaline medium. The reaction is: \[ S_{8(s)} + aOH^{-} \rightarrow bS_{(aq)}^{2-} + cS_{2}O_{3}^{2-} + dH_{2}O_{(l)} \] ### Step-by-Step Solution: 1. **Identify Oxidation States**: - Sulfur in \( S_8 \) has an oxidation state of 0. - In \( S^{2-} \), the oxidation state is -2. - In \( S_2O_3^{2-} \), we need to calculate the oxidation state of sulfur. 2. **Calculate Oxidation State of Sulfur in \( S_2O_3^{2-} \)**: - Let the oxidation state of sulfur be \( x \). - The equation for the oxidation state is: \[ 2x + 3(-2) = -2 \] \[ 2x - 6 = -2 \implies 2x = 4 \implies x = 2 \] - Thus, in \( S_2O_3^{2-} \), sulfur has an oxidation state of +2. 3. **Write Half-Reactions**: - **Reduction Half-Reaction**: \[ S_8 + 16e^{-} \rightarrow 8S^{2-} \] - **Oxidation Half-Reaction**: \[ S + 2OH^{-} \rightarrow S_2O_3^{2-} + H_2O + 2e^{-} \] 4. **Balance Electrons**: - To balance the electrons, we need to multiply the oxidation half-reaction by 8: \[ 8S + 16OH^{-} \rightarrow 8S_2O_3^{2-} + 8H_2O + 16e^{-} \] 5. **Combine Half-Reactions**: - Combine the reduction and oxidation half-reactions: \[ S_8 + 16OH^{-} \rightarrow 8S^{2-} + 8S_2O_3^{2-} + 8H_2O \] 6. **Simplify the Equation**: - Divide the entire equation by 2 to simplify: \[ S_8 + 8OH^{-} \rightarrow 4S^{2-} + 4S_2O_3^{2-} + 4H_2O \] 7. **Identify Coefficients**: - From the balanced equation, we can identify: - \( a = 8 \) - \( b = 4 \) - \( c = 4 \) - \( d = 4 \) ### Final Answer: The value of \( a \) is **8**.
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