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For the reaction A((g))rarr(B)((g)), the...

For the reaction `A_((g))rarr(B)_((g))`, the value of the equilibrium constant at 300 K and I atm is equal to 100.0. The value of `Delta_rG` for the reaction at 300 K and I atm in J `mol^(-1)` is - xR, where x is `"_______"`
(Rounded of to the nearest integer) (R=8.31 J `mol^(-1)K^(-1) and "In" 10 = 2.3)`

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To solve the problem, we need to find the value of \( x \) in the equation \( \Delta_r G = -xR \) for the reaction \( A_{(g)} \rightleftharpoons B_{(g)} \) at equilibrium, given that the equilibrium constant \( K \) is 100.0 at 300 K and 1 atm. ### Step-by-Step Solution: 1. **Understand the relationship between Gibbs free energy and equilibrium constant:** The relationship between the standard Gibbs free energy change (\( \Delta_r G^\circ \)) and the equilibrium constant (\( K \)) is given by the equation: \[ \Delta_r G^\circ = -RT \ln K \] where \( R \) is the universal gas constant and \( T \) is the temperature in Kelvin. 2. **Convert \( K \) to natural logarithm:** Since we are given \( K = 100.0 \), we can convert it to natural logarithm using the relationship: \[ \ln K = \log_{10} K \times 2.303 \] We know that \( \log_{10} 100 = 2 \) because \( 100 = 10^2 \). Therefore: \[ \ln K = 2 \times 2.303 = 4.606 \] 3. **Substitute the values into the Gibbs free energy equation:** Now we can substitute \( R = 8.31 \, \text{J mol}^{-1} \text{K}^{-1} \), \( T = 300 \, \text{K} \), and \( \ln K = 4.606 \) into the Gibbs free energy equation: \[ \Delta_r G^\circ = - (8.31 \, \text{J mol}^{-1} \text{K}^{-1})(300 \, \text{K})(4.606) \] 4. **Calculate \( \Delta_r G^\circ \):** Performing the multiplication: \[ \Delta_r G^\circ = - (8.31 \times 300 \times 4.606) \] First, calculate \( 8.31 \times 300 = 2493 \). Then, calculate \( 2493 \times 4.606 \approx 11449.58 \). Therefore: \[ \Delta_r G^\circ \approx -11449.58 \, \text{J mol}^{-1} \] 5. **Express \( \Delta_r G^\circ \) in terms of \( -xR \):** We have \( \Delta_r G^\circ = -xR \). Thus: \[ -xR = -11449.58 \] Since \( R = 8.31 \, \text{J mol}^{-1} \text{K}^{-1} \), we can express \( x \): \[ x = \frac{11449.58}{8.31} \approx 1377.4 \] 6. **Round to the nearest integer:** Rounding \( 1377.4 \) gives us \( x \approx 1377 \). ### Final Answer: The value of \( x \) is \( \boxed{1377} \).
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