Home
Class 12
CHEMISTRY
The ionization enthalpy of Na^+ formatio...

The ionization enthalpy of `Na^+` formation from Nad is `495.8 kJ mol^(-1)`, while the electron gain enthalpy of Bris `-325.0 kJ mol^(-1)` .Given the lattice enthalpy of NaBr is `-728.4 kJ mol^(-1)` The energy for the formation of NaBr ionic solid is `(-)"______" xx 10^(-1)kJ "mol"^(-1)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the energy for the formation of NaBr ionic solid, we will use the following equation based on the Born-Haber cycle: \[ \Delta H_f^\circ = \Delta H_{ionization} + \Delta H_{electron \, gain} + \Delta H_{lattice} \] Where: - \(\Delta H_f^\circ\) is the enthalpy of formation of NaBr. - \(\Delta H_{ionization}\) is the ionization enthalpy of Na. - \(\Delta H_{electron \, gain}\) is the electron gain enthalpy of Br. - \(\Delta H_{lattice}\) is the lattice enthalpy of NaBr. ### Step 1: Write down the given values - Ionization enthalpy of Na: \(\Delta H_{ionization} = 495.8 \, kJ \, mol^{-1}\) - Electron gain enthalpy of Br: \(\Delta H_{electron \, gain} = -325.0 \, kJ \, mol^{-1}\) - Lattice enthalpy of NaBr: \(\Delta H_{lattice} = -728.4 \, kJ \, mol^{-1}\) ### Step 2: Substitute the values into the equation Now we substitute the values into the Born-Haber cycle equation: \[ \Delta H_f^\circ = 495.8 + (-325.0) + (-728.4) \] ### Step 3: Perform the calculations 1. Calculate \(495.8 - 325.0\): \[ 495.8 - 325.0 = 170.8 \] 2. Now add the lattice enthalpy: \[ 170.8 - 728.4 = -557.6 \] ### Step 4: Final result Thus, the energy for the formation of NaBr ionic solid is: \[ \Delta H_f^\circ = -557.6 \, kJ \, mol^{-1} \] To express it in the required format: \[ \Delta H_f^\circ = -5.576 \times 10^2 \, kJ \, mol^{-1} \] ### Answer: The energy for the formation of NaBr ionic solid is \(-5.576 \times 10^2 \, kJ \, mol^{-1}\).
Promotional Banner

Topper's Solved these Questions

  • JEE MAIN 2021

    JEE MAINS PREVIOUS YEAR|Exercise CHEMISTRY (SECTION-A)|20 Videos
  • JEE MAIN 2021

    JEE MAINS PREVIOUS YEAR|Exercise CHEMISTRY (SECTION-B)|10 Videos
  • JEE MAIN 2021

    JEE MAINS PREVIOUS YEAR|Exercise SECTION-A|100 Videos
  • JEE MAIN

    JEE MAINS PREVIOUS YEAR|Exercise CHEMISTRY|150 Videos
  • JEE MAIN 2022

    JEE MAINS PREVIOUS YEAR|Exercise Question|561 Videos

Similar Questions

Explore conceptually related problems

The enthalpy of solution of sodium chloride is 4 kJ mol^(-1) and its enthalpy of hydration of ion is -784 kJ mol^(-1) . Then the lattice enthalpy of NaCl (in kJ mol^(-1) ) is

Ionisation of energy F^(ɵ) is 320 kJ mol^(-1) . The electronic gain enthalpy of fluorine would be

The ionization enthalpy of sulphur is 1014 kJ mol^(-1) . If its electronegativity is 2.4, what is its electron gain enthalpy?

Lattice energy of NaCl(s) is -790 kJ " mol"^(-1) and enthalpy of hydration is -785 kJ " mol"^(-1) . Calculate enthalpy of solution of NaCl(s).

The standard enthalpy of formation of NH_(3) is -46.0 kJ mol^(-1) . If the enthalpy of formation of H_(2) from its atoms is -436 kJ mol^(-1) and that of N_(2) is -7112kJ mol^(-1) , the average bond enthalpy of N-H bond in NH_(3) is :-

With the help of given following information find deltaH_f(NaBr)^@ Ionisation enthalpy of Na(g) to Na^+ is 495.8KJ/mole, electron given enthalpy of Br is -325KJ/mole & Lattice enthalpy of NaBr(s) -747KJ/mole.

JEE MAINS PREVIOUS YEAR-JEE MAIN 2021-SECTION-B
  1. 0.4 g mixture of NaOH, Na2CO3, and some inert N impurities was first t...

    Text Solution

    |

  2. HC-=CH overset(Red Hot Fe) underset (AlCl3) to [X] overset (CO,HCl//Al...

    Text Solution

    |

  3. The ionization enthalpy of Na^+ formation from Nad is 495.8 kJ mol^(-1...

    Text Solution

    |

  4. For a chemical reaction A+ B hArr C + D (Deltar H^0 = 80 KJ "mol"^(-...

    Text Solution

    |

  5. Find the significant figure in 50000.020 xx 10^(-3)

    Text Solution

    |

  6. An exothermic reaction X to Y has an activation energy 30 KJ "mol"^(-1...

    Text Solution

    |

  7. Consider the following reaction MnO4^(-) + 8 H^(+) 5e^(-) to Mn^(...

    Text Solution

    |

  8. For a real gas following vander waal equation is obtained P(Vm-b) =RT ...

    Text Solution

    |

  9. A homogeneous ideal gaseous reaction AB(2(g)) ƒhArr A((g)) + 2B((g)) ...

    Text Solution

    |

  10. Dichromate ion is treated with base, the oxidation number of Cr in the...

    Text Solution

    |

  11. 224 mL of SO(2(g)) at 298 K and 1 atm is passed through 100 mL of 0.1 ...

    Text Solution

    |

  12. 3.12 g of oxygen is adsorbed on 1.2 g of platinum metal. The volume of...

    Text Solution

    |

  13. Number of bridging CO ligands in [Mn2 (CO)(10)] is .

    Text Solution

    |

  14. The total number of amines among the following which can be synthesize...

    Text Solution

    |

  15. Among the following allotropic forms of sulphur , the number of allotr...

    Text Solution

    |

  16. The formula of a gaseous hydrocarbon which requires 6 times of its own...

    Text Solution

    |

  17. The volume occupied by 4.75g of acetylene gas at 50^(@)C and 740 mmH...

    Text Solution

    |

  18. C6H6 freezes at 5.5^(@)C. The temperature at which a solution 10 g of ...

    Text Solution

    |

  19. The magnitude of the change in oxidising power of the MnO4^(-)//Mn^(2+...

    Text Solution

    |

  20. The solubility product of PbI2 is 8.0 xx 10^(-9). The solubility of le...

    Text Solution

    |