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For a chemical reaction A+ B hArr C + D ...

For a chemical reaction A+ B `hArr C + D (Delta_r H^0 = 80 ` KJ `"mol"^(-1))` the entropy change `Delta_r S^0` depends on the temperature T (in K) as `(Delta_r S^0 = 2T(J K^(-1) "mol"^(-1))` .
Minimum temperature at which it will become spontaneous is ___________ K. (Integer)

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To determine the minimum temperature at which the reaction becomes spontaneous, we can use the Gibbs free energy equation: \[ \Delta G = \Delta H - T \Delta S \] For the reaction to be spontaneous, \(\Delta G\) must be less than 0: \[ \Delta H - T \Delta S < 0 \] This can be rearranged to: \[ \Delta H < T \Delta S \] ### Step 1: Convert \(\Delta H\) from kJ to J Given that \(\Delta H = 80 \, \text{kJ/mol}\), we need to convert this to joules: \[ \Delta H = 80 \times 10^3 \, \text{J/mol} = 80000 \, \text{J/mol} \] ### Step 2: Write the expression for \(\Delta S\) The entropy change \(\Delta S\) is given as: \[ \Delta S = 2T \, \text{(J K}^{-1} \text{mol}^{-1}) \] ### Step 3: Substitute \(\Delta H\) and \(\Delta S\) into the inequality Now we substitute \(\Delta H\) and \(\Delta S\) into the inequality: \[ 80000 < T \cdot (2T) \] This simplifies to: \[ 80000 < 2T^2 \] ### Step 4: Solve for \(T\) Rearranging gives: \[ T^2 > \frac{80000}{2} \] \[ T^2 > 40000 \] Taking the square root of both sides: \[ T > \sqrt{40000} \] Calculating the square root: \[ T > 200 \, \text{K} \] ### Conclusion The minimum temperature at which the reaction will become spontaneous is: \[ \boxed{200} \, \text{K} \]
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