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Two polyatomic ideal gases are mixed tog...

Two polyatomic ideal gases are mixed together temperatures `T_1` and `T_2`, number of molecules `N_1` and `N_2`, mass of particles `m_1` and `m_2`, degrees of freedom `f_1` and `f_2` find final temperatures of mixtures.

A

`(N_1 T_1 + N_2 T_2)/(N_1 + N_2)`

B

`(N_1 f_1 T_1 + N_2 f_2 T_2)/(N_1 f_1 + N_2 f_2)`

C

`(f_1 T_1 + f_2 T_2)/(f_1 + f_2)`

D

`(T_1 + T_2)/2`

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The correct Answer is:
To find the final temperature of the mixture of two polyatomic ideal gases, we can follow these steps: ### Step-by-Step Solution: 1. **Identify Given Variables:** - Let \( T_1 \) and \( T_2 \) be the initial temperatures of the two gases. - Let \( N_1 \) and \( N_2 \) be the number of molecules of the two gases. - Let \( m_1 \) and \( m_2 \) be the masses of the particles of the two gases. - Let \( f_1 \) and \( f_2 \) be the degrees of freedom of the two gases. 2. **Calculate the Equivalent Degrees of Freedom:** - The equivalent degrees of freedom \( f_{eq} \) for the mixture can be calculated using: \[ f_{eq} = \frac{N_1 f_1 + N_2 f_2}{N_1 + N_2} \] 3. **Calculate the Internal Energy of Each Gas:** - The internal energy \( U \) of an ideal gas can be expressed as: \[ U = \frac{N}{N_A} \cdot \frac{f}{2} R T \] - For gas 1, the internal energy \( U_1 \) is: \[ U_1 = \frac{N_1}{N_A} \cdot \frac{f_1}{2} R T_1 \] - For gas 2, the internal energy \( U_2 \) is: \[ U_2 = \frac{N_2}{N_A} \cdot \frac{f_2}{2} R T_2 \] 4. **Total Internal Energy of the Mixture:** - The total internal energy \( U_{total} \) of the mixture is: \[ U_{total} = U_1 + U_2 = \frac{N_1 f_1 R T_1}{2 N_A} + \frac{N_2 f_2 R T_2}{2 N_A} \] 5. **Internal Energy of the Mixture:** - The internal energy of the mixture can also be expressed as: \[ U_{mix} = \frac{N_1 + N_2}{N_A} \cdot \frac{f_{eq}}{2} R T \] - Where \( T \) is the final temperature of the mixture. 6. **Set the Total Internal Energy Equal to the Internal Energy of the Mixture:** - Equating the two expressions for internal energy: \[ \frac{N_1 f_1 R T_1}{2 N_A} + \frac{N_2 f_2 R T_2}{2 N_A} = \frac{N_1 + N_2}{N_A} \cdot \frac{f_{eq}}{2} R T \] 7. **Cancel Common Terms:** - Cancel \( R \) and \( N_A \) from both sides: \[ \frac{N_1 f_1 T_1}{2} + \frac{N_2 f_2 T_2}{2} = \frac{(N_1 + N_2) f_{eq}}{2} T \] 8. **Solve for Final Temperature \( T \):** - Rearranging gives: \[ T = \frac{N_1 f_1 T_1 + N_2 f_2 T_2}{N_1 f_1 + N_2 f_2} \] ### Final Result: The final temperature \( T \) of the mixture is given by: \[ T = \frac{N_1 f_1 T_1 + N_2 f_2 T_2}{N_1 f_1 + N_2 f_2} \]
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