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Which of the following statements regard...

Which of the following statements regarding `1,3`- dimethyl cyclobutane is/are correct?

A

Both cis and trans forms are optically active.

B

Both cis and trans forms are optically inactive.

C

The cis form is optically active, while the trans form is optically inactive.

D

The trans form is optically active, while the cis form is optically inactive.

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statements regarding 1,3-dimethylcyclobutane are correct, we will analyze the structure and optical activity of both the cis and trans forms of the compound. ### Step-by-Step Solution: 1. **Understanding the Structure**: - 1,3-dimethylcyclobutane consists of a cyclobutane ring with two methyl groups attached at the 1 and 3 positions. - The two possible configurations for these methyl groups are cis (both groups on the same side of the ring) and trans (the groups on opposite sides of the ring). 2. **Drawing the Structures**: - **Cis form**: Both methyl groups are on the same side (wedge-wedge or dash-dash). - **Trans form**: One methyl group is on a wedge (up) and the other on a dash (down). 3. **Analyzing Optical Activity**: - A compound is optically active if it does not possess any symmetry elements that would allow it to be superimposed on its mirror image. - For a compound to be optically inactive, it must have either a center of symmetry, a plane of symmetry, or an axis of symmetry. 4. **Checking for Symmetry**: - **Cis form**: When you draw a plane of symmetry through the center of the cyclobutane, it divides the molecule into two equal halves. Therefore, the cis form has a plane of symmetry and is optically inactive. - **Trans form**: Similarly, if you draw a plane of symmetry for the trans form, it also divides the molecule into two equal halves. Thus, the trans form also has a plane of symmetry and is optically inactive. 5. **Conclusion**: - Since both the cis and trans forms of 1,3-dimethylcyclobutane have a plane of symmetry, both are optically inactive. ### Final Answer: The correct statement regarding 1,3-dimethylcyclobutane is that **both cis and trans forms are optically inactive**.
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CENGAGE CHEMISTRY ENGLISH-ISOMERISM-Multiple choice questions (Exercise)
  1. Which of the following statements are correct?

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  2. Which of the following statement regarding 1,2- dimethylcyclopropane (...

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  3. Which of the following statements regarding 1,3- dimethyl cyclobutane ...

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  4. Which of the following statements regarding 1,3- dimethl cyclobutane i...

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  5. Which of the following statements regarding 1,2-dimethyl cyclo-pentane...

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  6. The configuration of sugars is related to glyceraldehyde and that of a...

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  7. Which of the following statement are true?

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  8. Which of the following statements are correct?

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  9. Which of the following statements are wrong?

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  10. Which of the following statements are correct?

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  11. Which of the following statements are wrong?

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  12. Which of the following statements are correct?

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  13. Which of the following statements are correct?

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  14. Which of the following statements are wrong?

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  15. Only two isomeric monochloro derivatives are possible for

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  16. Keto-enol tautomerism is observed in

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  17. Which of the following has/have asymmetric carbon atom?

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  18. The molecule (s) that will have dipole moment is/are:

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  19. Which one of the following compounds will show geometrical isomerism ?

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  20. Tautomerism is exhibited by :

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