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Which of the following statements regard...

Which of the following statements regarding `1,3`- dimethl cyclobutane is/are correct?

A

The cis has plane of symmetry, while the trans form has both plane and centre of symmetry.

B

The cis form has both plane and centre of symmetry, while the trans form has only plane of symmetry.

C

Both have only plane of symmetry.

D

Neither of them has any element of symmetry.

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The correct Answer is:
To determine which statements regarding 1,3-dimethylcyclobutane are correct, we need to analyze the structure of the compound and the definitions of symmetry elements. ### Step 1: Understand the Structure of 1,3-Dimethylcyclobutane 1,3-Dimethylcyclobutane is a cyclobutane ring with two methyl groups attached at the 1 and 3 positions. The structure can exist in two geometric isomers: cis and trans. ### Step 2: Identify the Geometric Isomers - **Cis-1,3-Dimethylcyclobutane**: Both methyl groups are on the same side of the cyclobutane ring. - **Trans-1,3-Dimethylcyclobutane**: The methyl groups are on opposite sides of the cyclobutane ring. ### Step 3: Analyze the Symmetry Elements 1. **Cis Isomer**: - **Plane of Symmetry**: The cis isomer has a plane of symmetry because if you were to draw an imaginary line through the middle of the molecule, the two halves would be mirror images of each other. - **Center of Symmetry**: The cis isomer does not have a center of symmetry because there is no point in the molecule from which equal groups are present at equal distances in opposite directions. 2. **Trans Isomer**: - **Plane of Symmetry**: The trans isomer has a plane of symmetry as well. - **Center of Symmetry**: The trans isomer also has a center of symmetry because there exists a point in the molecule from which equal groups are present at equal distances in opposite directions. ### Step 4: Evaluate the Statements 1. **Statement 1**: "Cis has a plane of symmetry while trans has both plane and center of symmetry." - **Correct**: This statement is true as explained above. 2. **Statement 2**: "Cis form has both plane and center of symmetry while trans form has only plane of symmetry." - **Incorrect**: The cis form only has a plane of symmetry, not a center of symmetry. 3. **Statement 3**: "Both have only plane of symmetry." - **Incorrect**: The trans form has both plane and center of symmetry. 4. **Statement 4**: "Neither of them has any element of symmetry." - **Incorrect**: Both isomers have symmetry elements. ### Conclusion The only correct statement regarding 1,3-dimethylcyclobutane is the first one. Therefore, the answer is option number 1.
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CENGAGE CHEMISTRY ENGLISH-ISOMERISM-Multiple choice questions (Exercise)
  1. Which of the following statement regarding 1,2- dimethylcyclopropane (...

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  2. Which of the following statements regarding 1,3- dimethyl cyclobutane ...

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  3. Which of the following statements regarding 1,3- dimethl cyclobutane i...

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  4. Which of the following statements regarding 1,2-dimethyl cyclo-pentane...

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  5. The configuration of sugars is related to glyceraldehyde and that of a...

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  6. Which of the following statement are true?

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  7. Which of the following statements are correct?

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  8. Which of the following statements are wrong?

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  9. Which of the following statements are correct?

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  10. Which of the following statements are wrong?

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  11. Which of the following statements are correct?

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  12. Which of the following statements are correct?

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  13. Which of the following statements are wrong?

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  14. Only two isomeric monochloro derivatives are possible for

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  15. Keto-enol tautomerism is observed in

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  16. Which of the following has/have asymmetric carbon atom?

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  17. The molecule (s) that will have dipole moment is/are:

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  18. Which one of the following compounds will show geometrical isomerism ?

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  19. Tautomerism is exhibited by :

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  20. The correct statements about the compound given below is :

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