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Which of the following statements are wr...

Which of the following statements are wrong?

A

Ethyl benzene is the chain isomer of xylene.

B

Alkenes can exhibit the position, chain, functional, and geometrical isomerism.

C

Esters and carboxylic acids are examples of metamerism.

D

Metamers belong to different classes of compounds.

Text Solution

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The correct Answer is:
To determine which statements are wrong regarding isomerism, let's analyze each statement step by step. ### Step 1: Analyze Statement A **Statement A:** Ethyl benzene is a chain isomer of xylene. - **Structure of Ethyl Benzene:** Ethyl benzene consists of a benzene ring with an ethyl group (C2H5) attached. - **Structure of Xylene:** Xylene can refer to three isomers: ortho-xylene, meta-xylene, and para-xylene, each having two methyl groups (CH3) attached to the benzene ring. **Conclusion for Statement A:** Ethyl benzene and xylene are not chain isomers; they belong to different structural categories. Therefore, this statement is **incorrect**. ### Step 2: Analyze Statement B **Statement B:** Alkenes can exhibit position, chain, functional, and geometrical isomerism. - **Position Isomerism:** Alkenes can have different positions for the double bond. - **Chain Isomerism:** Alkenes can have different carbon skeletons (e.g., straight-chain vs. branched). - **Functional Isomerism:** Alkenes can be compared with other functional groups, but they primarily exhibit isomerism among alkenes. - **Geometrical Isomerism:** Alkenes can have cis-trans isomers due to restricted rotation around the double bond. **Conclusion for Statement B:** This statement is **correct** as alkenes can exhibit all these types of isomerism. ### Step 3: Analyze Statement C **Statement C:** Esters and carboxylic acids are examples of metamerism. - **Definition of Metamerism:** Metamerism occurs when compounds with the same functional group have different alkyl chains on either side of the functional group. - **Esters and Carboxylic Acids:** Esters (RCOOR') and carboxylic acids (RCOOH) are not metamers because they belong to different functional groups. **Conclusion for Statement C:** This statement is **incorrect** as esters and carboxylic acids do not exhibit metamerism. ### Step 4: Analyze Statement D **Statement D:** Metamers belong to different classes of compounds. - **Understanding Metamerism:** Metamers must belong to the same functional group but differ in the arrangement of carbon chains. - **Conclusion:** Since metamers belong to the same functional group, this statement is **incorrect**. ### Final Conclusion Based on the analysis: - **Incorrect Statements:** A, C, and D. - **Correct Statement:** B. ### Summary of Incorrect Statements: - Statement A: Ethyl benzene is a chain isomer of xylene. (Incorrect) - Statement C: Esters and carboxylic acids are examples of metamerism. (Incorrect) - Statement D: Metamers belong to different classes of compounds. (Incorrect)

To determine which statements are wrong regarding isomerism, let's analyze each statement step by step. ### Step 1: Analyze Statement A **Statement A:** Ethyl benzene is a chain isomer of xylene. - **Structure of Ethyl Benzene:** Ethyl benzene consists of a benzene ring with an ethyl group (C2H5) attached. - **Structure of Xylene:** Xylene can refer to three isomers: ortho-xylene, meta-xylene, and para-xylene, each having two methyl groups (CH3) attached to the benzene ring. ...
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CENGAGE CHEMISTRY ENGLISH-ISOMERISM-Multiple choice questions (Exercise)
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  7. Which of the following statements are wrong?

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  8. Which of the following statements are correct?

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  9. Which of the following statements are wrong?

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  10. Which of the following statements are correct?

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  11. Which of the following statements are correct?

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  12. Which of the following statements are wrong?

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  13. Only two isomeric monochloro derivatives are possible for

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  15. Which of the following has/have asymmetric carbon atom?

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  16. The molecule (s) that will have dipole moment is/are:

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  17. Which one of the following compounds will show geometrical isomerism ?

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  19. The correct statements about the compound given below is :

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