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An alkali metal hydride (NaH) reacts wit...

An alkali metal hydride (NaH) reacts with diborane is 'A' to give a tetrahedral compound 'B' which is extensilve used as reducing agent in organic synthesis. The compoun d 'A' and'B' respectively. Are

A

`CH_(3)COCH_(3)` and `B_(3)N_(3)H_(6)`

B

`(C_(2)H_(5))_(2)O` and `NaBH_(4)`

C

`C_(2)H_(6)` and `C_(2)H_(5)Na`

D

`C_(6)H_(6)` and `NaBH_(4)`

Text Solution

Verified by Experts

The correct Answer is:
B

`underset(" Sod. hydride ")(2NaOH) + B_(2)H_(6) overset((C_(2)H_(5))_(2)O (A))underset(" Diethyl ether ")rarr underset((" Tetrahedral complex "))underset(" Sod. Borohydride (B) ")(2Na^(+)[BH_(4)]^(-))`
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