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When benzenediazonium chloride is heated...

When benzenediazonium chloride is heated with fluoro boric acid, fluorobenzene is formed. This reaction is called

A

Balz Schiemann reation

B

Gattermann reaction

C

Sandmeyer reaction

D

Hoffmann bromamide reaction

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The correct Answer is:
To solve the question regarding the reaction of benzenediazonium chloride with fluoro boric acid, we can break down the process into clear steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in this reaction are benzenediazonium chloride (C6H5N2Cl) and fluoro boric acid (HBF4). 2. **Understand the Structure of Benzenediazonium Chloride**: Benzenediazonium chloride consists of a benzene ring (C6H5) attached to a diazonium group (N2+) and a chloride ion (Cl-). The diazonium group is a good leaving group. 3. **Reaction with Fluoro Boric Acid**: When benzenediazonium chloride is heated with fluoro boric acid, the diazonium group (N2) acts as a leaving group. The reaction can be summarized as: \[ C_6H_5N_2Cl + HBF_4 \rightarrow C_6H_5F + N_2 + HCl \] Here, the diazonium group (N2) leaves, and the fluorine from the fluoro boric acid replaces the diazonium group on the benzene ring. 4. **Formation of Fluorobenzene**: The product of this reaction is fluorobenzene (C6H5F), which is formed after the elimination of nitrogen gas (N2) and hydrochloric acid (HCl). 5. **Name of the Reaction**: This specific reaction is known as the **Bals-Skyman reaction**. It is a method for the synthesis of aryl fluorides from aryl diazonium salts. ### Final Answer: The reaction of benzenediazonium chloride with fluoro boric acid to form fluorobenzene is called the **Bals-Skyman reaction**. ---
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